(Deep) blue through-space conjugated TADF emitters based on [2.2]paracyclophanes

Eduard Spuling; Nidhi Sharma; Ifor Samuel; Eli Zysman-Colman; Stefan Bräse

doi:10.1039/C8CC04594A

(Deep) blue through-space conjugated TADF emitters based on [2.2]paracyclophanes

Eduard Spuling, Nidhi Sharma, Ifor Samuel, Eli Zysman-Colman, Stefan Bräse

Research output: Contribution to journal › Article › peer-review

Abstract

The first examples of through-space conjugated thermally activated delayed fluorescence (TADF) emitters based on a [2.2]para- cyclophane (PCP) skeleton with stacked (coplanar) donor-acceptor groups have been synthesized. The optoelectronic properties are studied by the relative configuration, cis (pseudo-geminal) and trans (pseudo-para), of the donor and acceptor groups.

Original language	English
Pages (from-to)	9278-9281
Journal	Chemical Communications
Volume	54
Issue number	67
Early online date	4 Jul 2018
DOIs	https://doi.org/10.1039/C8CC04594A
Publication status	Published - 28 Aug 2018

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10.1039/C8CC04594A

Cyclophane paper- submitted-ver 8
© 2018 the Authors. This work has been made available online in accordance with the publisher’s policies. This is the author created accepted version manuscript following peer review and as such may differ slightly from the final published version. The final published version of this work is available at https://doi.org/10.1039/C8CC04594A
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Cite this

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title = "(Deep) blue through-space conjugated TADF emitters based on [2.2]paracyclophanes",

abstract = "The first examples of through-space conjugated thermally activated delayed fluorescence (TADF) emitters based on a [2.2]para- cyclophane (PCP) skeleton with stacked (coplanar) donor-acceptor groups have been synthesized. The optoelectronic properties are studied by the relative configuration, cis (pseudo-geminal) and trans (pseudo-para), of the donor and acceptor groups.",

author = "Eduard Spuling and Nidhi Sharma and Ifor Samuel and Eli Zysman-Colman and Stefan Br{\"a}se",

note = "E. S. and S. B. acknowledge funding from DFG in the frame of SFB1176 (projects A4, B3 and C6) and KSOP (fellowship to E. S.). E. Z.-C. and I. D. W. S. thank the Engineering and Physical Sciences Research Council (EPSRC) (No. EP/P010482/1) for financial support. I.D.W.S. also acknowledges support from a Royal Society Wolfson Research Merit Award.",

year = "2018",

month = aug,

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doi = "10.1039/C8CC04594A",

language = "English",

volume = "54",

pages = "9278--9281",

journal = "Chemical Communications",

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T1 - (Deep) blue through-space conjugated TADF emitters based on [2.2]paracyclophanes

AU - Spuling, Eduard

AU - Sharma, Nidhi

AU - Samuel, Ifor

AU - Zysman-Colman, Eli

AU - Bräse, Stefan

N1 - E. S. and S. B. acknowledge funding from DFG in the frame of SFB1176 (projects A4, B3 and C6) and KSOP (fellowship to E. S.). E. Z.-C. and I. D. W. S. thank the Engineering and Physical Sciences Research Council (EPSRC) (No. EP/P010482/1) for financial support. I.D.W.S. also acknowledges support from a Royal Society Wolfson Research Merit Award.

PY - 2018/8/28

Y1 - 2018/8/28

N2 - The first examples of through-space conjugated thermally activated delayed fluorescence (TADF) emitters based on a [2.2]para- cyclophane (PCP) skeleton with stacked (coplanar) donor-acceptor groups have been synthesized. The optoelectronic properties are studied by the relative configuration, cis (pseudo-geminal) and trans (pseudo-para), of the donor and acceptor groups.

AB - The first examples of through-space conjugated thermally activated delayed fluorescence (TADF) emitters based on a [2.2]para- cyclophane (PCP) skeleton with stacked (coplanar) donor-acceptor groups have been synthesized. The optoelectronic properties are studied by the relative configuration, cis (pseudo-geminal) and trans (pseudo-para), of the donor and acceptor groups.

UR - http://www.rsc.org/suppdata/c8/cc/c8cc04594a/c8cc04594a1.pdf

U2 - 10.1039/C8CC04594A

DO - 10.1039/C8CC04594A

M3 - Article

SN - 1359-7345

VL - 54

SP - 9278

EP - 9281

JO - Chemical Communications

JF - Chemical Communications

IS - 67

ER -

(Deep) blue through-space conjugated TADF emitters based on [2.2]paracyclophanes

Abstract

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Other files and links

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Thermally Activated Delayed Fluorescenc: Thermally Activated Delayed Fluorescence Materials for Displays and Photodynamic Theory

TADF Emitters for OLEDs - Ifor Samuel: TADF Emitters for OLEDs

TADF Emitters for OLEDs - Eli Zysman: TADF Emitters for OLEDs