Decarboxylation of aromatic carboxylic acids by gold(I)-N-heterocyclic carbene (NHC) complexes

Stephanie Dupuy; Faima Lazreg; Alexandra M. Z. Slawin; Catherine S. J. Cazin; Steven P. Nolan

doi:10.1039/c1cc10917k

Decarboxylation of aromatic carboxylic acids by gold(I)-N-heterocyclic carbene (NHC) complexes

Stephanie Dupuy, Faima Lazreg, Alexandra M. Z. Slawin, Catherine S. J. Cazin, Steven P. Nolan

Research output: Contribution to journal › Article › peer-review

Abstract

A recently isolated gold(I) complex, [Au(IPr)(OH)], permits the transformation of carboxylic acids to the corresponding decarboxylated gold(I)-aryl complex without the use of silver co-catalyst under mild reaction conditions.

Original language	English
Pages (from-to)	5455-5457
Number of pages	3
Journal	Chemical Communications
Volume	47
Issue number	19
Early online date	1 Apr 2011
DOIs	https://doi.org/10.1039/c1cc10917k
Publication status	Published - 2011

Keywords

C-H BONDS
CATALYZED PROTODECARBOXYLATION
COUPLING REACTIONS
BENZOIC-ACIDS
ARYL HALIDES
ARYLATION
METAL

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10.1039/c1cc10917k

Molecular assembly using gold catalysis: Molecular assembly using gold catalysis
Nolan, S. P. (PI)
EPSRC
1/01/10 → 31/12/12
Project: Standard

Cite this

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title = "Decarboxylation of aromatic carboxylic acids by gold(I)-N-heterocyclic carbene (NHC) complexes",

abstract = "A recently isolated gold(I) complex, [Au(IPr)(OH)], permits the transformation of carboxylic acids to the corresponding decarboxylated gold(I)-aryl complex without the use of silver co-catalyst under mild reaction conditions.",

keywords = "C-H BONDS, CATALYZED PROTODECARBOXYLATION, COUPLING REACTIONS, BENZOIC-ACIDS, ARYL HALIDES, ARYLATION, METAL",

author = "Stephanie Dupuy and Faima Lazreg and Slawin, {Alexandra M. Z.} and Cazin, {Catherine S. J.} and Nolan, {Steven P.}",

year = "2011",

doi = "10.1039/c1cc10917k",

language = "English",

volume = "47",

pages = "5455--5457",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

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T1 - Decarboxylation of aromatic carboxylic acids by gold(I)-N-heterocyclic carbene (NHC) complexes

AU - Dupuy, Stephanie

AU - Lazreg, Faima

AU - Slawin, Alexandra M. Z.

AU - Cazin, Catherine S. J.

AU - Nolan, Steven P.

PY - 2011

Y1 - 2011

N2 - A recently isolated gold(I) complex, [Au(IPr)(OH)], permits the transformation of carboxylic acids to the corresponding decarboxylated gold(I)-aryl complex without the use of silver co-catalyst under mild reaction conditions.

AB - A recently isolated gold(I) complex, [Au(IPr)(OH)], permits the transformation of carboxylic acids to the corresponding decarboxylated gold(I)-aryl complex without the use of silver co-catalyst under mild reaction conditions.

KW - C-H BONDS

KW - CATALYZED PROTODECARBOXYLATION

KW - COUPLING REACTIONS

KW - BENZOIC-ACIDS

KW - ARYL HALIDES

KW - ARYLATION

KW - METAL

U2 - 10.1039/c1cc10917k

DO - 10.1039/c1cc10917k

M3 - Article

SN - 1359-7345

VL - 47

SP - 5455

EP - 5457

JO - Chemical Communications

JF - Chemical Communications

IS - 19

ER -

Decarboxylation of aromatic carboxylic acids by gold(I)-N-heterocyclic carbene (NHC) complexes

Abstract

Keywords

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Projects

Molecular assembly using gold catalysis: Molecular assembly using gold catalysis

Cite this