Cyclodextrins as Second Sphere Ligands for Transition Metal Complexes—The X‐Ray Crystal Structure of [Rh(cod)(NH3)2·α‐cyclodextrin][PF6]·6H2O

David R. Alston; Alexandra M.Z. Slawin; J. Fraser Stoddart; David J. Williams

doi:10.1002/anie.198507861

Cyclodextrins as Second Sphere Ligands for Transition Metal Complexes—The X‐Ray Crystal Structure of [Rh(cod)(NH₃)₂·α‐cyclodextrin][PF₆]·6H₂O

David R. Alston, Alexandra M.Z. Slawin, J. Fraser Stoddart^*, David J. Williams

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

86 Citations (Scopus)

Abstract

The structure of the 1:1 adduct of [Rh(cod)(NH₃)₂][PF₆] (cod = 1,5‐cyclooctadiene) and α‐cyclodextrin (α‐CD) has been elucidated by an X‐ray structure analysis. The tub‐shaped cod ligand lies almost exactly above the center of the α‐CD cavity, into which it partilly protudes. The two NH₃ ligands interact with four secondary OH groups. (Figure Presented.)

Original language	English
Pages (from-to)	786-787
Number of pages	2
Journal	Angewandte Chemie International Edition in English
Volume	24
Issue number	9
DOIs	https://doi.org/10.1002/anie.198507861
Publication status	Published - 1 Jan 1985

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@article{f3089cd9ba204782b35b2cec60758880,

title = "Cyclodextrins as Second Sphere Ligands for Transition Metal Complexes—The X‐Ray Crystal Structure of [Rh(cod)(NH3)2·α‐cyclodextrin][PF6]·6H2O",

abstract = "The structure of the 1:1 adduct of [Rh(cod)(NH3)2][PF6] (cod = 1,5‐cyclooctadiene) and α‐cyclodextrin (α‐CD) has been elucidated by an X‐ray structure analysis. The tub‐shaped cod ligand lies almost exactly above the center of the α‐CD cavity, into which it partilly protudes. The two NH3 ligands interact with four secondary OH groups. (Figure Presented.)",

author = "Alston, {David R.} and Slawin, {Alexandra M.Z.} and Stoddart, {J. Fraser} and Williams, {David J.}",

year = "1985",

month = jan,

day = "1",

doi = "10.1002/anie.198507861",

language = "English",

volume = "24",

pages = "786--787",

journal = "Angewandte Chemie International Edition in English",

issn = "0570-0833",

publisher = "Wiley-VCH, Weinheim",

number = "9",

}

Cyclodextrins as Second Sphere Ligands for Transition Metal Complexes—The X‐Ray Crystal Structure of [Rh(cod)(NH₃)₂·α‐cyclodextrin][PF₆]·6H₂O. / Alston, David R.; Slawin, Alexandra M.Z.; Stoddart, J. Fraser et al.
In: Angewandte Chemie International Edition in English, Vol. 24, No. 9, 01.01.1985, p. 786-787.

Research output: Contribution to journal › Article › peer-review

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T1 - Cyclodextrins as Second Sphere Ligands for Transition Metal Complexes—The X‐Ray Crystal Structure of [Rh(cod)(NH3)2·α‐cyclodextrin][PF6]·6H2O

AU - Alston, David R.

AU - Slawin, Alexandra M.Z.

AU - Stoddart, J. Fraser

AU - Williams, David J.

PY - 1985/1/1

Y1 - 1985/1/1

N2 - The structure of the 1:1 adduct of [Rh(cod)(NH3)2][PF6] (cod = 1,5‐cyclooctadiene) and α‐cyclodextrin (α‐CD) has been elucidated by an X‐ray structure analysis. The tub‐shaped cod ligand lies almost exactly above the center of the α‐CD cavity, into which it partilly protudes. The two NH3 ligands interact with four secondary OH groups. (Figure Presented.)

AB - The structure of the 1:1 adduct of [Rh(cod)(NH3)2][PF6] (cod = 1,5‐cyclooctadiene) and α‐cyclodextrin (α‐CD) has been elucidated by an X‐ray structure analysis. The tub‐shaped cod ligand lies almost exactly above the center of the α‐CD cavity, into which it partilly protudes. The two NH3 ligands interact with four secondary OH groups. (Figure Presented.)

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DO - 10.1002/anie.198507861

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ER -

Cyclodextrins as Second Sphere Ligands for Transition Metal Complexes—The X‐Ray Crystal Structure of [Rh(cod)(NH₃)₂·α‐cyclodextrin][PF₆]·6H₂O

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