Crystal structures of dibenzo[ce]-1,2-dithiine and its related oxides

S M  Aucott; H L  Milton; S D  Robertson; A M Z  Slawin; J D  Woollins

doi:10.1002/hc.20101

Crystal structures of dibenzo[ce]-1,2-dithiine and its related oxides

S M Aucott, H L Milton, S D Robertson, A M Z Slawin, J D Woollins

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Abstract

The X-ray structures of dibenzo[ce]-1,2dithiine, dibenzo[ce]-1,2-dithiine-5,5-dioxide, dibenzo[ce]-1,2-dithiine-5,5,6-trioxide, and dibenzo[ce]-1, 2-dithiine-5,5,6,6-tetraoxide are reported and compared with the related "constrained" naphthalene derivatives. The S-S distances vary upon oxidation of the S centers in the order S-S < SO-S > SO2-S < SO2-SO > SO2-SO2 i.e. the most oxidized sulfur atoms do not lead to the longest bond lengths. (c) 2005 Wiley Periodicals, Inc.

Original language	English
Pages (from-to)	346-351
Number of pages	6
Journal	Heteroatom Chemistry
Volume	16
Issue number	5
DOIs	https://doi.org/10.1002/hc.20101
Publication status	Published - 2005

Keywords

9,10-DIHYDROPHENANTHRENES

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title = "Crystal structures of dibenzo[ce]-1,2-dithiine and its related oxides",

abstract = "The X-ray structures of dibenzo[ce]-1,2dithiine, dibenzo[ce]-1,2-dithiine-5,5-dioxide, dibenzo[ce]-1,2-dithiine-5,5,6-trioxide, and dibenzo[ce]-1, 2-dithiine-5,5,6,6-tetraoxide are reported and compared with the related {"}constrained{"} naphthalene derivatives. The S-S distances vary upon oxidation of the S centers in the order S-S < SO-S > SO2-S < SO2-SO > SO2-SO2 i.e. the most oxidized sulfur atoms do not lead to the longest bond lengths. (c) 2005 Wiley Periodicals, Inc.",

keywords = "9,10-DIHYDROPHENANTHRENES",

author = "Aucott, \{S M\} and Milton, \{H L\} and Robertson, \{S D\} and Slawin, \{A M Z\} and Woollins, \{J D\}",

year = "2005",

doi = "10.1002/hc.20101",

language = "English",

volume = "16",

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journal = "Heteroatom Chemistry",

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TY - JOUR

T1 - Crystal structures of dibenzo[ce]-1,2-dithiine and its related oxides

AU - Aucott, S M

AU - Milton, H L

AU - Robertson, S D

AU - Slawin, A M Z

AU - Woollins, J D

PY - 2005

Y1 - 2005

N2 - The X-ray structures of dibenzo[ce]-1,2dithiine, dibenzo[ce]-1,2-dithiine-5,5-dioxide, dibenzo[ce]-1,2-dithiine-5,5,6-trioxide, and dibenzo[ce]-1, 2-dithiine-5,5,6,6-tetraoxide are reported and compared with the related "constrained" naphthalene derivatives. The S-S distances vary upon oxidation of the S centers in the order S-S < SO-S > SO2-S < SO2-SO > SO2-SO2 i.e. the most oxidized sulfur atoms do not lead to the longest bond lengths. (c) 2005 Wiley Periodicals, Inc.

AB - The X-ray structures of dibenzo[ce]-1,2dithiine, dibenzo[ce]-1,2-dithiine-5,5-dioxide, dibenzo[ce]-1,2-dithiine-5,5,6-trioxide, and dibenzo[ce]-1, 2-dithiine-5,5,6,6-tetraoxide are reported and compared with the related "constrained" naphthalene derivatives. The S-S distances vary upon oxidation of the S centers in the order S-S < SO-S > SO2-S < SO2-SO > SO2-SO2 i.e. the most oxidized sulfur atoms do not lead to the longest bond lengths. (c) 2005 Wiley Periodicals, Inc.

KW - 9,10-DIHYDROPHENANTHRENES

UR - https://www.scopus.com/pages/publications/24144475502

U2 - 10.1002/hc.20101

DO - 10.1002/hc.20101

M3 - Article

SN - 1042-7163

VL - 16

SP - 346

EP - 351

JO - Heteroatom Chemistry

JF - Heteroatom Chemistry

IS - 5

ER -

Crystal structures of dibenzo[ce]-1,2-dithiine and its related oxides

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