TY - JOUR
T1 - Crystal structures of dibenzo[ce]-1,2-dithiine and its related oxides
AU - Aucott, S M
AU - Milton, H L
AU - Robertson, S D
AU - Slawin, A M Z
AU - Woollins, J D
PY - 2005
Y1 - 2005
N2 - The X-ray structures of dibenzo[ce]-1,2dithiine, dibenzo[ce]-1,2-dithiine-5,5-dioxide, dibenzo[ce]-1,2-dithiine-5,5,6-trioxide, and dibenzo[ce]-1, 2-dithiine-5,5,6,6-tetraoxide are reported and compared with the related "constrained" naphthalene derivatives. The S-S distances vary upon oxidation of the S centers in the order S-S < SO-S > SO2-S < SO2-SO > SO2-SO2 i.e. the most oxidized sulfur atoms do not lead to the longest bond lengths. (c) 2005 Wiley Periodicals, Inc.
AB - The X-ray structures of dibenzo[ce]-1,2dithiine, dibenzo[ce]-1,2-dithiine-5,5-dioxide, dibenzo[ce]-1,2-dithiine-5,5,6-trioxide, and dibenzo[ce]-1, 2-dithiine-5,5,6,6-tetraoxide are reported and compared with the related "constrained" naphthalene derivatives. The S-S distances vary upon oxidation of the S centers in the order S-S < SO-S > SO2-S < SO2-SO > SO2-SO2 i.e. the most oxidized sulfur atoms do not lead to the longest bond lengths. (c) 2005 Wiley Periodicals, Inc.
KW - 9,10-DIHYDROPHENANTHRENES
UR - http://www.scopus.com/inward/record.url?scp=24144475502&partnerID=8YFLogxK
U2 - 10.1002/hc.20101
DO - 10.1002/hc.20101
M3 - Article
SN - 1042-7163
VL - 16
SP - 346
EP - 351
JO - Heteroatom Chemistry
JF - Heteroatom Chemistry
IS - 5
ER -