Crystal structure of the 'mixed-layer' Aurivillius phase Bi5TiNbWO15

A  Snedden; D O  Charkin; V A  Dolgikh; P  Lightfoot

doi:10.1016/j.jssc.2004.08.021

Crystal structure of the 'mixed-layer' Aurivillius phase Bi5TiNbWO15

A Snedden, D O Charkin, V A Dolgikh, P Lightfoot

Research output: Contribution to journal › Article › peer-review

Abstract

The crystal structure of the Aurivillius phase Bi5TiNbWO15 has been analyzed in detail using powder X-ray and neutron diffraction. The structure can be described as a regular intergrowth of alternating single and double perovskite-like layers sandwiched between fluorite-like bismuth oxide layers, such that the layer sequence is ... [WO4]-[Bi2O2]-[BiTiNbO7]-[Bi2O2] .... There is complete ordering of tungsten within the B sites of the single perovskite layer, so that the structure can be described as a direct intergrowth of the 'component' Aurivillius phases B2WO6 and Bi3TiNbO9. At 25degreesC the structure adopts the polar orthorhombic space group 12cm, a = 5.4231(2) Angstrom, b = 5.4027(2) Angstrom, c = 41.744(1)Angstrom. (C) 2004 Elsevier Inc. All rights reserved.

Original language	English
Pages (from-to)	180-184
Number of pages	5
Journal	Journal of Solid State Chemistry
Volume	178
DOIs	https://doi.org/10.1016/j.jssc.2004.08.021
Publication status	Published - Jan 2005

Keywords

Aurivillius phase
ferroelectric
neutron diffraction
bismuth oxide
FERROELECTRIC PROPERTIES
BISMUTH COMPOUNDS
FAMILY
BI3TINBO9
CHEMISTRY
BI2WO6

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title = "Crystal structure of the 'mixed-layer' Aurivillius phase Bi5TiNbWO15",

abstract = "The crystal structure of the Aurivillius phase Bi5TiNbWO15 has been analyzed in detail using powder X-ray and neutron diffraction. The structure can be described as a regular intergrowth of alternating single and double perovskite-like layers sandwiched between fluorite-like bismuth oxide layers, such that the layer sequence is ... [WO4]-[Bi2O2]-[BiTiNbO7]-[Bi2O2] .... There is complete ordering of tungsten within the B sites of the single perovskite layer, so that the structure can be described as a direct intergrowth of the 'component' Aurivillius phases B2WO6 and Bi3TiNbO9. At 25degreesC the structure adopts the polar orthorhombic space group 12cm, a = 5.4231(2) Angstrom, b = 5.4027(2) Angstrom, c = 41.744(1)Angstrom. (C) 2004 Elsevier Inc. All rights reserved.",

keywords = "Aurivillius phase, ferroelectric, neutron diffraction, bismuth oxide, FERROELECTRIC PROPERTIES, BISMUTH COMPOUNDS, FAMILY, BI3TINBO9, CHEMISTRY, BI2WO6",

author = "A Snedden and Charkin, \{D O\} and Dolgikh, \{V A\} and P Lightfoot",

year = "2005",

month = jan,

doi = "10.1016/j.jssc.2004.08.021",

language = "English",

volume = "178",

pages = "180--184",

journal = "Journal of Solid State Chemistry",

issn = "0022-4596",

publisher = "Academic Press/Elsevier ",

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TY - JOUR

T1 - Crystal structure of the 'mixed-layer' Aurivillius phase Bi5TiNbWO15

AU - Snedden, A

AU - Charkin, D O

AU - Dolgikh, V A

AU - Lightfoot, P

PY - 2005/1

Y1 - 2005/1

N2 - The crystal structure of the Aurivillius phase Bi5TiNbWO15 has been analyzed in detail using powder X-ray and neutron diffraction. The structure can be described as a regular intergrowth of alternating single and double perovskite-like layers sandwiched between fluorite-like bismuth oxide layers, such that the layer sequence is ... [WO4]-[Bi2O2]-[BiTiNbO7]-[Bi2O2] .... There is complete ordering of tungsten within the B sites of the single perovskite layer, so that the structure can be described as a direct intergrowth of the 'component' Aurivillius phases B2WO6 and Bi3TiNbO9. At 25degreesC the structure adopts the polar orthorhombic space group 12cm, a = 5.4231(2) Angstrom, b = 5.4027(2) Angstrom, c = 41.744(1)Angstrom. (C) 2004 Elsevier Inc. All rights reserved.

AB - The crystal structure of the Aurivillius phase Bi5TiNbWO15 has been analyzed in detail using powder X-ray and neutron diffraction. The structure can be described as a regular intergrowth of alternating single and double perovskite-like layers sandwiched between fluorite-like bismuth oxide layers, such that the layer sequence is ... [WO4]-[Bi2O2]-[BiTiNbO7]-[Bi2O2] .... There is complete ordering of tungsten within the B sites of the single perovskite layer, so that the structure can be described as a direct intergrowth of the 'component' Aurivillius phases B2WO6 and Bi3TiNbO9. At 25degreesC the structure adopts the polar orthorhombic space group 12cm, a = 5.4231(2) Angstrom, b = 5.4027(2) Angstrom, c = 41.744(1)Angstrom. (C) 2004 Elsevier Inc. All rights reserved.

KW - Aurivillius phase

KW - ferroelectric

KW - neutron diffraction

KW - bismuth oxide

KW - FERROELECTRIC PROPERTIES

KW - BISMUTH COMPOUNDS

KW - FAMILY

KW - BI3TINBO9

KW - CHEMISTRY

KW - BI2WO6

UR - https://www.scopus.com/pages/publications/13444274755

U2 - 10.1016/j.jssc.2004.08.021

DO - 10.1016/j.jssc.2004.08.021

M3 - Article

SN - 0022-4596

VL - 178

SP - 180

EP - 184

JO - Journal of Solid State Chemistry

JF - Journal of Solid State Chemistry

ER -

Crystal structure of the 'mixed-layer' Aurivillius phase Bi5TiNbWO15

Abstract

Keywords

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