Crystal structure of 2-phenyl-2λ4,3-ditelluratetracyclo[5.5.2.04,13.010,14]tetradeca-1(12),4,6,10,13-pentaen-2-ylium trifluoromethanesulfonate

Louise M. Diamond; Alexandra M Z Slawin; J. Derek Woollins

doi:10.1107/S1600536814018170

Crystal structure of 2-phenyl-2λ4,3-ditelluratetracyclo[5.5.2.04,13.010,14]tetradeca-1(12),4,6,10,13-pentaen-2-ylium trifluoromethanesulfonate

Louise M. Diamond, Alexandra M Z Slawin, J. Derek Woollins^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

In the title compound, C₁₈H₁₃Te₂ ⁺CF₃O₃S^-, the Te^IIatom of the cation and one O atom of the trifluoromethanesulfonate counter-ion form a close-to-linear Te - Te - O system, with a Te - Te - O angle of 172.3 (1)° and a Te - O distance of 2.816 (5) Å, which may suggest the presence of a three-centre-four-electron (3c-4e) bond. Secondary Te⋯O interactions [3.003 (4) and 3.016 (4) Å], involving the second Te^IIatom of the binuclear molecule, are also noted, resulting in a supramolecular layer in the bc plane.

Original language	English
Pages (from-to)	o1003-o1004
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	70
Issue number	9
DOIs	https://doi.org/10.1107/S1600536814018170
Publication status	Published - 1 Jan 2014

Keywords

acenaphthene
crystal structure
tellurium
triflate

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10.1107/S1600536814018170

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@article{5bcd57c260e4458685ce13acec9521c5,

title = "Crystal structure of 2-phenyl-2λ4,3-ditelluratetracyclo[5.5.2.04,13.010,14]tetradeca-1(12),4,6,10,13-pentaen-2-ylium trifluoromethanesulfonate",

abstract = "In the title compound, C18H13Te2 +CF3O3S-, the TeIIatom of the cation and one O atom of the trifluoromethanesulfonate counter-ion form a close-to-linear Te - Te - O system, with a Te - Te - O angle of 172.3 (1)° and a Te - O distance of 2.816 (5) {\AA}, which may suggest the presence of a three-centre-four-electron (3c-4e) bond. Secondary Te⋯O interactions [3.003 (4) and 3.016 (4) {\AA}], involving the second TeIIatom of the binuclear molecule, are also noted, resulting in a supramolecular layer in the bc plane.",

keywords = "acenaphthene, crystal structure, tellurium, triflate",

author = "Diamond, \{Louise M.\} and Slawin, \{Alexandra M Z\} and Woollins, \{J. Derek\}",

year = "2014",

month = jan,

day = "1",

doi = "10.1107/S1600536814018170",

language = "English",

volume = "70",

pages = "o1003--o1004",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

number = "9",

}

Crystal structure of 2-phenyl-2λ4,3-ditelluratetracyclo[5.5.2.04,13.010,14]tetradeca-1(12),4,6,10,13-pentaen-2-ylium trifluoromethanesulfonate. / Diamond, Louise M.; Slawin, Alexandra M Z; Woollins, J. Derek.
In: Acta Crystallographica Section E: Structure Reports Online, Vol. 70, No. 9, 01.01.2014, p. o1003-o1004.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Crystal structure of 2-phenyl-2λ4,3-ditelluratetracyclo[5.5.2.04,13.010,14]tetradeca-1(12),4,6,10,13-pentaen-2-ylium trifluoromethanesulfonate

AU - Diamond, Louise M.

AU - Slawin, Alexandra M Z

AU - Woollins, J. Derek

PY - 2014/1/1

Y1 - 2014/1/1

N2 - In the title compound, C18H13Te2 +CF3O3S-, the TeIIatom of the cation and one O atom of the trifluoromethanesulfonate counter-ion form a close-to-linear Te - Te - O system, with a Te - Te - O angle of 172.3 (1)° and a Te - O distance of 2.816 (5) Å, which may suggest the presence of a three-centre-four-electron (3c-4e) bond. Secondary Te⋯O interactions [3.003 (4) and 3.016 (4) Å], involving the second TeIIatom of the binuclear molecule, are also noted, resulting in a supramolecular layer in the bc plane.

AB - In the title compound, C18H13Te2 +CF3O3S-, the TeIIatom of the cation and one O atom of the trifluoromethanesulfonate counter-ion form a close-to-linear Te - Te - O system, with a Te - Te - O angle of 172.3 (1)° and a Te - O distance of 2.816 (5) Å, which may suggest the presence of a three-centre-four-electron (3c-4e) bond. Secondary Te⋯O interactions [3.003 (4) and 3.016 (4) Å], involving the second TeIIatom of the binuclear molecule, are also noted, resulting in a supramolecular layer in the bc plane.

KW - acenaphthene

KW - crystal structure

KW - tellurium

KW - triflate

UR - https://www.scopus.com/pages/publications/84907010625

U2 - 10.1107/S1600536814018170

DO - 10.1107/S1600536814018170

M3 - Article

AN - SCOPUS:84907010625

SN - 1600-5368

VL - 70

SP - o1003-o1004

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 9

ER -

Crystal structure of 2-phenyl-2λ4,3-ditelluratetracyclo[5.5.2.04,13.010,14]tetradeca-1(12),4,6,10,13-pentaen-2-ylium trifluoromethanesulfonate

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