Crystal structure of 2-benzoylamino-it N'-(4-hydroxybenzylidene)-3-(thiophen-2-yl)prop-2-enohydrazide

Karanth N. Subbulakshmi; Badiadka Narayana; Hemmige S. Yathirajan; Jerry P. Jasinski; Ravindranath S. Rathore; Christopher Glidewell

doi:10.1107/S2056989016010975

Crystal structure of 2-benzoylamino-it N'-(4-hydroxybenzylidene)-3-(thiophen-2-yl)prop-2-enohydrazide

Karanth N. Subbulakshmi, Badiadka Narayana, Hemmige S. Yathirajan, Jerry P. Jasinski, Ravindranath S. Rathore, Christopher Glidewell

School of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

In the title compound, C₂₁H₁₇N₃O₃S, the non-H atoms, apart from those in the benzoyl group, are almost coplanar (r.m.s. deviation = 0.049 Å) and the benzoyl group is almost orthogonal to the plane of the rest of the molecule [dihedral angle = 80.34(6)º]. In the crystal, a combination of N---H···O and asymmetric bifurcated O---H···(N,O) hydrogen bonds link the molecules into a three-dimensional network. Weak C---H···O interactions are also observed.

Original language	English
Pages (from-to)	1099-1102
Number of pages	4
Journal	Acta Crystallographica Section E
Volume	72
Issue number	8
Early online date	12 Jul 2016
DOIs	https://doi.org/10.1107/S2056989016010975
Publication status	Published - 1 Aug 2016

Keywords

Crystal structure
Supramolecular structure
Molecular conformation
Hydrogen bonding

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Data underpinning - Crystal structure of 2-benzoylamino-it N'-(4-hydroxybenzylidene)-3-(thiophen-2-yl)prop-2-enohydrazide
Subbulakshmi, K. N. (Creator), Narayana, B. (Creator), Yathirajan, H. S. (Creator), Jasinski, J. P. (Creator), Rathore, R. S. (Creator) & Glidewell, C. (Creator), Cambridge Crystallographic Data Centre, 2016
DOI: 10.5517/ccdc.csd.cc1m1mhs, http://dx.doi.org/10.5517/ccdc.csd.cc1m1mhs
Dataset

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@article{383f70b73dfd46cbb65fc2ed0b1e9177,

title = "Crystal structure of 2-benzoylamino-it N'-(4-hydroxybenzylidene)-3-(thiophen-2-yl)prop-2-enohydrazide",

abstract = "In the title compound, C21H17N3O3S, the non-H atoms, apart from those in the benzoyl group, are almost coplanar (r.m.s. deviation = 0.049 {\AA}) and the benzoyl group is almost orthogonal to the plane of the rest of the molecule [dihedral angle = 80.34(6)º]. In the crystal, a combination of N---H···O and asymmetric bifurcated O---H···(N,O) hydrogen bonds link the molecules into a three-dimensional network. Weak C---H···O interactions are also observed.",

keywords = "Crystal structure, Supramolecular structure, Molecular conformation, Hydrogen bonding",

author = "Subbulakshmi, {Karanth N.} and Badiadka Narayana and Yathirajan, {Hemmige S.} and Jasinski, {Jerry P.} and Rathore, {Ravindranath S.} and Christopher Glidewell",

note = "JPJ acknowledges the NSF–MRI program (grant No. 1039027) for funds to purchase the X-ray diffractometer.",

year = "2016",

month = aug,

day = "1",

doi = "10.1107/S2056989016010975",

language = "English",

volume = "72",

pages = "1099--1102",

journal = "Acta Crystallographica Section E",

issn = "2056-9890",

publisher = "International Union of Crystallography",

number = "8",

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TY - JOUR

T1 - Crystal structure of 2-benzoylamino-it N'-(4-hydroxybenzylidene)-3-(thiophen-2-yl)prop-2-enohydrazide

AU - Subbulakshmi, Karanth N.

AU - Narayana, Badiadka

AU - Yathirajan, Hemmige S.

AU - Jasinski, Jerry P.

AU - Rathore, Ravindranath S.

AU - Glidewell, Christopher

N1 - JPJ acknowledges the NSF–MRI program (grant No. 1039027) for funds to purchase the X-ray diffractometer.

PY - 2016/8/1

Y1 - 2016/8/1

N2 - In the title compound, C21H17N3O3S, the non-H atoms, apart from those in the benzoyl group, are almost coplanar (r.m.s. deviation = 0.049 Å) and the benzoyl group is almost orthogonal to the plane of the rest of the molecule [dihedral angle = 80.34(6)º]. In the crystal, a combination of N---H···O and asymmetric bifurcated O---H···(N,O) hydrogen bonds link the molecules into a three-dimensional network. Weak C---H···O interactions are also observed.

AB - In the title compound, C21H17N3O3S, the non-H atoms, apart from those in the benzoyl group, are almost coplanar (r.m.s. deviation = 0.049 Å) and the benzoyl group is almost orthogonal to the plane of the rest of the molecule [dihedral angle = 80.34(6)º]. In the crystal, a combination of N---H···O and asymmetric bifurcated O---H···(N,O) hydrogen bonds link the molecules into a three-dimensional network. Weak C---H···O interactions are also observed.

KW - Crystal structure

KW - Supramolecular structure

KW - Molecular conformation

KW - Hydrogen bonding

U2 - 10.1107/S2056989016010975

DO - 10.1107/S2056989016010975

M3 - Article

SN - 2056-9890

VL - 72

SP - 1099

EP - 1102

JO - Acta Crystallographica Section E

JF - Acta Crystallographica Section E

IS - 8

ER -

Crystal structure of 2-benzoylamino-it N'-(4-hydroxybenzylidene)-3-(thiophen-2-yl)prop-2-enohydrazide

Abstract

Keywords

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Data underpinning - Crystal structure of 2-benzoylamino-it N'-(4-hydroxybenzylidene)-3-(thiophen-2-yl)prop-2-enohydrazide

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