CO2 activation by manganese pincer complexes through different modes of metal-ligand cooperation (Special issue on Breaking bonds over many timescales: in celebration of Robin Perutz’s 70th birthday)

Amit Kumar; Prosenjit Daw; Noel A. E. Jalapa; Gregory Leitus; Linda Shimon; Yehoshoa Ben-David; David Milstein

doi:10.1039/C9DT03088C

CO₂activation by manganese pincer complexes through different modes of metal-ligand cooperation (Special issue on Breaking bonds over many timescales: in celebration of Robin Perutz’s 70th birthday)

Amit Kumar
, Prosenjit Daw
, Noel A. E. Jalapa
, Gregory Leitus
, Linda Shimon
, Yehoshoa Ben-David
, David Milstein

School of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

We report here the activation of CO₂ using two Mn-PNN pincer complexes that can exhibit different modes of metal–ligand cooperation amido/amino mode that involves [1,2]-activation of CO₂ and dearomatization/aromatization mode that involves [1,3]-activation of CO₂. We also compare their catalytic activity for CO₂ hydrogenation.

Original language	English
Pages (from-to)	14580-14584
Journal	Dalton Transactions
Volume	48
Early online date	4 Sept 2019
DOIs	https://doi.org/10.1039/C9DT03088C
Publication status	Published - 21 Oct 2019

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Amit Kumar
- ak336st-andrews.acuk
- School of Chemistry - UKRI Future Leaders Fellow
Person: Academic - Research

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Kumar, A., Daw, P., Jalapa, N. A. E., Leitus, G., Shimon, L., Ben-David, Y., & Milstein, D. (2019). CO₂activation by manganese pincer complexes through different modes of metal-ligand cooperation (Special issue on Breaking bonds over many timescales: in celebration of Robin Perutz’s 70th birthday). Dalton Transactions, 48, 14580-14584. https://doi.org/10.1039/C9DT03088C

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title = "CO2 activation by manganese pincer complexes through different modes of metal-ligand cooperation (Special issue on Breaking bonds over many timescales: in celebration of Robin Perutz{\textquoteright}s 70th birthday)",

abstract = "We report here the activation of CO2 using two Mn-PNN pincer complexes that can exhibit different modes of metal–ligand cooperation amido/amino mode that involves [1,2]-activation of CO2 and dearomatization/aromatization mode that involves [1,3]-activation of CO2. We also compare their catalytic activity for CO2 hydrogenation.",

author = "Amit Kumar and Prosenjit Daw and Jalapa, \{Noel A. E.\} and Gregory Leitus and Linda Shimon and Yehoshoa Ben-David and David Milstein",

note = "P. D. and A. K. are thankful to the Planning and Budgeting Committee of the Council for Higher Education of Israel for a postdoctoral fellowship. PD also thanks Weizmann Institute of Science for a senior postdoctoral fellowship. N. A. E.-J. thanks Mr Armando Jinich for a postdoctoral fellowship. ",

year = "2019",

month = oct,

day = "21",

doi = "10.1039/C9DT03088C",

language = "English",

volume = "48",

pages = "14580--14584",

journal = "Dalton Transactions",

issn = "1477-9226",

publisher = "Royal Society of Chemistry",

}

Kumar, A, Daw, P, Jalapa, NAE, Leitus, G, Shimon, L, Ben-David, Y & Milstein, D 2019, 'CO₂activation by manganese pincer complexes through different modes of metal-ligand cooperation (Special issue on Breaking bonds over many timescales: in celebration of Robin Perutz’s 70th birthday)', Dalton Transactions, vol. 48, pp. 14580-14584. https://doi.org/10.1039/C9DT03088C

CO₂activation by manganese pincer complexes through different modes of metal-ligand cooperation (Special issue on Breaking bonds over many timescales: in celebration of Robin Perutz’s 70th birthday). / Kumar, Amit; Daw, Prosenjit; Jalapa, Noel A. E. et al.
In: Dalton Transactions, Vol. 48, 21.10.2019, p. 14580-14584.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - CO2 activation by manganese pincer complexes through different modes of metal-ligand cooperation (Special issue on Breaking bonds over many timescales: in celebration of Robin Perutz’s 70th birthday)

AU - Kumar, Amit

AU - Daw, Prosenjit

AU - Jalapa, Noel A. E.

AU - Leitus, Gregory

AU - Shimon, Linda

AU - Ben-David, Yehoshoa

AU - Milstein, David

N1 - P. D. and A. K. are thankful to the Planning and Budgeting Committee of the Council for Higher Education of Israel for a postdoctoral fellowship. PD also thanks Weizmann Institute of Science for a senior postdoctoral fellowship. N. A. E.-J. thanks Mr Armando Jinich for a postdoctoral fellowship.

PY - 2019/10/21

Y1 - 2019/10/21

N2 - We report here the activation of CO2 using two Mn-PNN pincer complexes that can exhibit different modes of metal–ligand cooperation amido/amino mode that involves [1,2]-activation of CO2 and dearomatization/aromatization mode that involves [1,3]-activation of CO2. We also compare their catalytic activity for CO2 hydrogenation.

AB - We report here the activation of CO2 using two Mn-PNN pincer complexes that can exhibit different modes of metal–ligand cooperation amido/amino mode that involves [1,2]-activation of CO2 and dearomatization/aromatization mode that involves [1,3]-activation of CO2. We also compare their catalytic activity for CO2 hydrogenation.

U2 - 10.1039/C9DT03088C

DO - 10.1039/C9DT03088C

M3 - Article

SN - 1477-9226

VL - 48

SP - 14580

EP - 14584

JO - Dalton Transactions

JF - Dalton Transactions

ER -

CO2 activation by manganese pincer complexes through different modes of metal-ligand cooperation (Special issue on Breaking bonds over many timescales: in celebration of Robin Perutz’s 70th birthday)

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CO₂activation by manganese pincer complexes through different modes of metal-ligand cooperation (Special issue on Breaking bonds over many timescales: in celebration of Robin Perutz’s 70th birthday)