Correlating Pt-P bond lengths and Pt-P coupling constants

Paul G. Waddell, Alexandra M. Z. Slawin, J. Derek Woollins

Research output: Contribution to journalArticlepeer-review

36 Citations (Scopus)

Abstract

The X-ray structures of (5) cis-PtBr2(P(OMe)(3))(2), (6) cis-PtBr2(P(OMe)(2)Ph)(2), (7) cis-PtBr2(P(OMe)Ph-2)(2), (8) cis-PtBr2(PPh3)(2), (9) cis-PtI2(P(OMe)(3))(2), (10) cis-PtI2(P(OMe)(2)Ph)(2), (11) cis-PtI2(P(OMe)Ph-2)(2) and (12) cis-PtI2(PPh3)(2) are reported and compared with the previously reported chloride analogues. The magnitude of the J{Pt-P} varies linearly with the Pt-P bond length (l(Pt-P) = 2.421 - J/24255) for these 12 complexes.

Original languageEnglish
Pages (from-to)8620-8625
Number of pages6
JournalDalton Transactions
Volume39
Issue number37
DOIs
Publication statusPublished - 16 Aug 2010

Keywords

  • Nuclear-magnetic-resonance
  • X-ray-structure
  • Tertiary phosphine complexes
  • Transition-metal-complexes
  • Solid-state structures
  • Platinum(ii) complexes
  • Crystal-structures
  • Molecular-structure
  • Phosphorus ligands
  • Stacking compounds

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