Correlating Electronic Structures to Electrochemiluminescence of Cationic Ir Complexes

Eli Zysman-Colman; Kalen Swanick; Sébastien Ladouceur; Zhifeng Ding

doi:10.1039/C3RA43134G

Correlating Electronic Structures to Electrochemiluminescence of Cationic Ir Complexes

Eli Zysman-Colman, Kalen Swanick, Sébastien Ladouceur, Zhifeng Ding

Research output: Contribution to journal › Article › peer-review

30 Citations (Scopus)

Abstract

Electrochemiluminescence (ECL) of heteroleptic cationic iridium complexes is correlated to their structures in order to get insight into tuning their emission wavelength and intensity. While the installation of fluorine and tert-butyl substituents on the ligands increases the electrochemical gap and promotes blue shifts in ECL emission, it reduces ECL efficiencies.

Original language	English
Pages (from-to)	19961-19964
Journal	RSC Advances
Volume	3
DOIs	https://doi.org/10.1039/C3RA43134G
Publication status	Published - 2013

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title = "Correlating Electronic Structures to Electrochemiluminescence of Cationic Ir Complexes",

abstract = "Electrochemiluminescence (ECL) of heteroleptic cationic iridium complexes is correlated to their structures in order to get insight into tuning their emission wavelength and intensity. While the installation of fluorine and tert-butyl substituents on the ligands increases the electrochemical gap and promotes blue shifts in ECL emission, it reduces ECL efficiencies.",

author = "Eli Zysman-Colman and Kalen Swanick and S{\'e}bastien Ladouceur and Zhifeng Ding",

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AU - Swanick, Kalen

AU - Ladouceur, Sébastien

AU - Ding, Zhifeng

PY - 2013

Y1 - 2013

N2 - Electrochemiluminescence (ECL) of heteroleptic cationic iridium complexes is correlated to their structures in order to get insight into tuning their emission wavelength and intensity. While the installation of fluorine and tert-butyl substituents on the ligands increases the electrochemical gap and promotes blue shifts in ECL emission, it reduces ECL efficiencies.

AB - Electrochemiluminescence (ECL) of heteroleptic cationic iridium complexes is correlated to their structures in order to get insight into tuning their emission wavelength and intensity. While the installation of fluorine and tert-butyl substituents on the ligands increases the electrochemical gap and promotes blue shifts in ECL emission, it reduces ECL efficiencies.

U2 - 10.1039/C3RA43134G

DO - 10.1039/C3RA43134G

M3 - Article

SN - 2046-2069

VL - 3

SP - 19961

EP - 19964

JO - RSC Advances

JF - RSC Advances

ER -

Correlating Electronic Structures to Electrochemiluminescence of Cationic Ir Complexes

Abstract

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