TY - JOUR
T1 - Copper(II) oxalate and oxamate complexes
AU - Novosad, Josef
AU - Messimeri, Argyro C.
AU - Papadimitriou, Christos D.
AU - Veltsistas, Panos G.
AU - Woollins, J. Derek
PY - 2000/12/1
Y1 - 2000/12/1
N2 - Reaction of CuII salts with phenanthroline and oxalate (ox) or oxamate (oxm) gives [Cu(phen)(ox)(H2O)]·H2O or [Cu(phen)(oxm)(H2O)]·H2O complexes while direct treatment of CuII salts with oxalate or oxamate gives [NH4]2[Cu(ox)2] and [Cu(oxm)2(H2O)2] respectively. The X-ray structures of one example of each system, aquo-oxamato-phenanthroline-copper(II)-dihydrate and the polymeric ammonium-bis(aquo)-tetraoxalato-dicopper(II)-dihydrate, are reported.
AB - Reaction of CuII salts with phenanthroline and oxalate (ox) or oxamate (oxm) gives [Cu(phen)(ox)(H2O)]·H2O or [Cu(phen)(oxm)(H2O)]·H2O complexes while direct treatment of CuII salts with oxalate or oxamate gives [NH4]2[Cu(ox)2] and [Cu(oxm)2(H2O)2] respectively. The X-ray structures of one example of each system, aquo-oxamato-phenanthroline-copper(II)-dihydrate and the polymeric ammonium-bis(aquo)-tetraoxalato-dicopper(II)-dihydrate, are reported.
UR - http://www.scopus.com/inward/record.url?scp=0034552413&partnerID=8YFLogxK
U2 - 10.1023/A:1007068914946
DO - 10.1023/A:1007068914946
M3 - Article
AN - SCOPUS:0034552413
SN - 0340-4285
VL - 25
SP - 664
EP - 669
JO - Transition Metal Chemistry
JF - Transition Metal Chemistry
IS - 6
ER -