Copper oxalate and oxamate complexes

Josef Novosad; Christos Papadimitriou; Panos G Veltsistas; John Derek Woollins

Copper oxalate and oxamate complexes

Josef Novosad, Christos Papadimitriou, Panos G Veltsistas, John Derek Woollins

Research output: Other contribution

Abstract

Reaction of Cu-II salts with phenanthroline and oxalate (ox) or oxamate (oxm) gives [Cu(phen)(ox)(H2O)] . H2O or [Cu(phen)(oxm)(H2O)] . H2O complexes while direct treatment of Cu-II salts with oxalate or oxamate gives [NH4](2)[Cu(ox)(2)] and [Cu(oxm)(2)(H2O)(2)] respectively. The X-ray structures of one example of each system, aquo-oxamato-phenanthroline-copper(II)-dihydrate and the polymeric ammonium-bis(aquo)-tetraoxalato-dicopper(II)-dihydrate, are reported.

Original language	English
Volume	25
Publication status	Published - Dec 2000

Keywords

X-RAY STRUCTURE
MAGNETIC-PROPERTIES
OXAMIC ACID
MU-OXAMIDO
LIGANDS
CRYSTAL
BRIDGES

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title = "Copper oxalate and oxamate complexes",

abstract = "Reaction of Cu-II salts with phenanthroline and oxalate (ox) or oxamate (oxm) gives [Cu(phen)(ox)(H2O)] . H2O or [Cu(phen)(oxm)(H2O)] . H2O complexes while direct treatment of Cu-II salts with oxalate or oxamate gives [NH4](2)[Cu(ox)(2)] and [Cu(oxm)(2)(H2O)(2)] respectively. The X-ray structures of one example of each system, aquo-oxamato-phenanthroline-copper(II)-dihydrate and the polymeric ammonium-bis(aquo)-tetraoxalato-dicopper(II)-dihydrate, are reported.",

keywords = "X-RAY STRUCTURE, MAGNETIC-PROPERTIES, OXAMIC ACID, MU-OXAMIDO, LIGANDS, CRYSTAL, BRIDGES",

author = "Josef Novosad and Christos Papadimitriou and Veltsistas, \{Panos G\} and Woollins, \{John Derek\}",

note = "Transit Met Chem",

year = "2000",

month = dec,

language = "English",

volume = "25",

type = "Other",

}

TY - GEN

T1 - Copper oxalate and oxamate complexes

AU - Novosad, Josef

AU - Papadimitriou, Christos

AU - Veltsistas, Panos G

AU - Woollins, John Derek

N1 - Transit Met Chem

PY - 2000/12

Y1 - 2000/12

N2 - Reaction of Cu-II salts with phenanthroline and oxalate (ox) or oxamate (oxm) gives [Cu(phen)(ox)(H2O)] . H2O or [Cu(phen)(oxm)(H2O)] . H2O complexes while direct treatment of Cu-II salts with oxalate or oxamate gives [NH4](2)[Cu(ox)(2)] and [Cu(oxm)(2)(H2O)(2)] respectively. The X-ray structures of one example of each system, aquo-oxamato-phenanthroline-copper(II)-dihydrate and the polymeric ammonium-bis(aquo)-tetraoxalato-dicopper(II)-dihydrate, are reported.

AB - Reaction of Cu-II salts with phenanthroline and oxalate (ox) or oxamate (oxm) gives [Cu(phen)(ox)(H2O)] . H2O or [Cu(phen)(oxm)(H2O)] . H2O complexes while direct treatment of Cu-II salts with oxalate or oxamate gives [NH4](2)[Cu(ox)(2)] and [Cu(oxm)(2)(H2O)(2)] respectively. The X-ray structures of one example of each system, aquo-oxamato-phenanthroline-copper(II)-dihydrate and the polymeric ammonium-bis(aquo)-tetraoxalato-dicopper(II)-dihydrate, are reported.

KW - X-RAY STRUCTURE

KW - MAGNETIC-PROPERTIES

KW - OXAMIC ACID

KW - MU-OXAMIDO

KW - LIGANDS

KW - CRYSTAL

KW - BRIDGES

M3 - Other contribution

VL - 25

ER -

Copper oxalate and oxamate complexes

Abstract

Keywords

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