Coordination polymers of ZnII and 5-methoxy isophthalate

Laura Jayne McCormick; Samuel Alexander Morris; Simon J. Teat; Matthew Joseph McPherson; Alexandra Martha Zoya Slawin; Russell Edward Morris

doi:10.1039/C5DT02924D

Coordination polymers of Zn^II and 5-methoxy isophthalate

Laura Jayne McCormick, Samuel Alexander Morris, Simon J. Teat, Matthew Joseph McPherson, Alexandra Martha Zoya Slawin, Russell Edward Morris

Research output: Contribution to journal › Article › peer-review

Abstract

Solvothermal reaction of Zn(OAc)₂ and 5-methoxy isophthalic acid (H₂MeOip) in aqueous alcohols ROH (R = H, Me, Et, or ⁱPr) affords four different novel coordination polymers. Zn₂(HMeOip)(MeOip)(OAc) (1) forms as a 1D 'ribbon of rings' polymer. Zn₆(MeOip)_4.5(HMeOip)(OH)₂(H₂O)₂·5.5H₂O (2) crystallises as a complex 3D framework. Zn(MeOip)(H₂O)₂ H₂O (3) is a 1D coordination polymer that contains almost planar strips of Zn(MeOip). compound 4, Zn₅(MeOip)₄(OH)₂(H₂O)₄·H₂O, obtained from aqueous ⁱPrOH, crystallises as a 2D polymer containing two crystallographically distinct Zn₅(OH)₂ clusters. Preliminary nitric oxide release experiments have been conducted.

Original language	English
Pages (from-to)	17686-17695
Journal	Dalton Transactions
Volume	44
Issue number	40
Early online date	21 Sept 2015
DOIs	https://doi.org/10.1039/C5DT02924D
Publication status	Published - 28 Oct 2015

Access to Document

10.1039/C5DT02924DLicence: CC BY

Morris_2015_DT_Coordination_CC
Copyright 2015 the Authors. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence (http://creativecommons.org/licenses/by/3.0/).
Final published version, 3.83 MB

Cite this

@article{3d2bb6584aa1473da68984828499fe07,

title = "Coordination polymers of ZnII and 5-methoxy isophthalate",

abstract = "Solvothermal reaction of Zn(OAc)2 and 5-methoxy isophthalic acid (H2MeOip) in aqueous alcohols ROH (R = H, Me, Et, or iPr) affords four different novel coordination polymers. Zn2(HMeOip)(MeOip)(OAc) (1) forms as a 1D 'ribbon of rings' polymer. Zn6(MeOip)4.5(HMeOip)(OH)2(H2O)2·5.5H2O (2) crystallises as a complex 3D framework. Zn(MeOip)(H2O)2 H2O (3) is a 1D coordination polymer that contains almost planar strips of Zn(MeOip). compound 4, Zn5(MeOip)4(OH)2(H2O)4·H2O, obtained from aqueous iPrOH, crystallises as a 2D polymer containing two crystallographically distinct Zn5(OH)2 clusters. Preliminary nitric oxide release experiments have been conducted.",

author = "McCormick, {Laura Jayne} and Morris, {Samuel Alexander} and Teat, {Simon J.} and McPherson, {Matthew Joseph} and Slawin, {Alexandra Martha Zoya} and Morris, {Russell Edward}",

note = "This work was funded by the British Heart Foundation (NH/11/8/29253) and the EPSRC (EP/K005499/1). ",

year = "2015",

month = oct,

day = "28",

doi = "10.1039/C5DT02924D",

language = "English",

volume = "44",

pages = "17686--17695",

journal = "Dalton Transactions",

issn = "1477-9226",

publisher = "ROYAL SOC CHEMISTRY",

number = "40",

}

TY - JOUR

T1 - Coordination polymers of ZnII and 5-methoxy isophthalate

AU - McCormick, Laura Jayne

AU - Morris, Samuel Alexander

AU - Teat, Simon J.

AU - McPherson, Matthew Joseph

AU - Slawin, Alexandra Martha Zoya

AU - Morris, Russell Edward

N1 - This work was funded by the British Heart Foundation (NH/11/8/29253) and the EPSRC (EP/K005499/1).

PY - 2015/10/28

Y1 - 2015/10/28

N2 - Solvothermal reaction of Zn(OAc)2 and 5-methoxy isophthalic acid (H2MeOip) in aqueous alcohols ROH (R = H, Me, Et, or iPr) affords four different novel coordination polymers. Zn2(HMeOip)(MeOip)(OAc) (1) forms as a 1D 'ribbon of rings' polymer. Zn6(MeOip)4.5(HMeOip)(OH)2(H2O)2·5.5H2O (2) crystallises as a complex 3D framework. Zn(MeOip)(H2O)2 H2O (3) is a 1D coordination polymer that contains almost planar strips of Zn(MeOip). compound 4, Zn5(MeOip)4(OH)2(H2O)4·H2O, obtained from aqueous iPrOH, crystallises as a 2D polymer containing two crystallographically distinct Zn5(OH)2 clusters. Preliminary nitric oxide release experiments have been conducted.

AB - Solvothermal reaction of Zn(OAc)2 and 5-methoxy isophthalic acid (H2MeOip) in aqueous alcohols ROH (R = H, Me, Et, or iPr) affords four different novel coordination polymers. Zn2(HMeOip)(MeOip)(OAc) (1) forms as a 1D 'ribbon of rings' polymer. Zn6(MeOip)4.5(HMeOip)(OH)2(H2O)2·5.5H2O (2) crystallises as a complex 3D framework. Zn(MeOip)(H2O)2 H2O (3) is a 1D coordination polymer that contains almost planar strips of Zn(MeOip). compound 4, Zn5(MeOip)4(OH)2(H2O)4·H2O, obtained from aqueous iPrOH, crystallises as a 2D polymer containing two crystallographically distinct Zn5(OH)2 clusters. Preliminary nitric oxide release experiments have been conducted.

UR - http://www.rsc.org/suppdata/c5/dt/c5dt02924d/c5dt02924d1.pdf

U2 - 10.1039/C5DT02924D

DO - 10.1039/C5DT02924D

M3 - Article

SN - 1477-9226

VL - 44

SP - 17686

EP - 17695

JO - Dalton Transactions

JF - Dalton Transactions

IS - 40

ER -

Coordination polymers of Zn^II and 5-methoxy isophthalate

Abstract

Access to Document

Other files and links

Fingerprint

Hemilabile switchable metal-organic: Hemilabile and switchable metal-organic frameworks

Structuring the Future: Structuring the Future - Underpinning world-leading science in EaStCHEM through cutting edge characterisation

Non-classic Crystal Growth: Non-classic Crystal Growth and New Catalysts