Coordination polymers of 5-alkoxy isophthalic acids

Laura J. McCormick; Samuel A. Morris; Alexandra M. Z. Slawin; Simon J. Teat; Russell E. Morris

doi:10.1021/acs.cgd.6b00853

Coordination polymers of 5-alkoxy isophthalic acids

Laura J. McCormick, Samuel A. Morris, Alexandra M. Z. Slawin, Simon J. Teat, Russell E. Morris

Research output: Contribution to journal › Article › peer-review

Abstract

The topology of coordination polymers containing 5-alkoxy isophthalic acids and first row transition metals was found to be dependent on the combination of solvent system used and length of the alkyl chain. Four different framework types were identified: Phase A, M₆(ROip)₅(OH)₂(H₂O)₄·xH₂O (M = Co and R = Et, Pr, or ⁿBu, or M = Zn and R = Et); Phase B, M₂(ROip)₂(H₂O) (M = Co or Zn and R = Et, Pr, ⁿBu, or ⁱBu, or M = Mn and R = ⁿBu or ⁱBu); Phase C, Zn₃(EtOip)₂(OH)₂; and Phase D, Zn₂(EtOip)₂(H₂O)₃. Preliminary screening of the NO storage and release capabilities of the Co-containing materials is also reported.

Original language	English
Pages (from-to)	5771-5780
Number of pages	10
Journal	Crystal Growth & Design
Volume	16
Issue number	10
Early online date	23 Aug 2016
DOIs	https://doi.org/10.1021/acs.cgd.6b00853
Publication status	Published - 5 Oct 2016

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10.1021/acs.cgd.6b00853

Hemilabile switchable metal-organic: Hemilabile and switchable metal-organic frameworks
Morris, R. E. (PI)
EPSRC
1/03/13 → 28/02/16
Project: Standard
Non-classic Crystal Growth: Non-classic Crystal Growth and New Catalysts
Zhou, W. (PI)
British Council
1/12/12 → 31/12/14
Project: Standard

Coordination polymers of 5-alkoxy isophthalic acids (dataset)
McCormick, L. J. (Creator), Morris, S. A. (Creator), Slawin, A. M. Z. (Creator), Teat, S. J. (Creator) & Morris, R. E. (Creator), Cambridge Crystallographic Data Centre, 2016
https://dx.doi.org/10.5517/ccdc.csd.cc1lp1x7 and 14 more links, https://dx.doi.org/10.5517/ccdc.csd.cc1lp1y8, https://dx.doi.org/10.5517/ccdc.csd.cc1lp1z9, https://dx.doi.org/10.5517/ccdc.csd.cc1lp20c, https://dx.doi.org/10.5517/ccdc.csd.cc1lp21d, https://dx.doi.org/10.5517/ccdc.csd.cc1lp22f, https://dx.doi.org/10.5517/ccdc.csd.cc1lp23g, https://dx.doi.org/10.5517/ccdc.csd.cc1lp24h, https://dx.doi.org/10.5517/ccdc.csd.cc1lp25j, https://dx.doi.org/10.5517/ccdc.csd.cc1lp26k, https://dx.doi.org/10.5517/ccdc.csd.cc1lp27l, https://dx.doi.org/10.5517/ccdc.csd.cc1lp28m, https://dx.doi.org/10.5517/ccdc.csd.cc1lp29n, https://dx.doi.org/10.5517/ccdc.csd.cc1lp2bp, https://dx.doi.org/10.5517/ccdc.csd.cc1lp2cq (show fewer)
Dataset

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@article{7c32521ef3a445788e3db184f4ab86e9,

title = "Coordination polymers of 5-alkoxy isophthalic acids",

abstract = "The topology of coordination polymers containing 5-alkoxy isophthalic acids and first row transition metals was found to be dependent on the combination of solvent system used and length of the alkyl chain. Four different framework types were identified: Phase A, M6(ROip)5(OH)2(H2O)4·xH2O (M = Co and R = Et, Pr, or nBu, or M = Zn and R = Et); Phase B, M2(ROip)2(H2O) (M = Co or Zn and R = Et, Pr, nBu, or iBu, or M = Mn and R = nBu or iBu); Phase C, Zn3(EtOip)2(OH)2; and Phase D, Zn2(EtOip)2(H2O)3. Preliminary screening of the NO storage and release capabilities of the Co-containing materials is also reported.",

author = "McCormick, {Laura J.} and Morris, {Samuel A.} and Slawin, {Alexandra M. Z.} and Teat, {Simon J.} and Morris, {Russell E.}",

note = "This work was funded by the British Heart Foundation (NH/11/8/29253) and the EPSRC (EP/K005499/1).",

year = "2016",

month = oct,

day = "5",

doi = "10.1021/acs.cgd.6b00853",

language = "English",

volume = "16",

pages = "5771--5780",

journal = "Crystal Growth & Design",

issn = "1528-7483",

publisher = "American Chemical Society (ACS)",

number = "10",

}

TY - JOUR

T1 - Coordination polymers of 5-alkoxy isophthalic acids

AU - McCormick, Laura J.

AU - Morris, Samuel A.

AU - Slawin, Alexandra M. Z.

AU - Teat, Simon J.

AU - Morris, Russell E.

N1 - This work was funded by the British Heart Foundation (NH/11/8/29253) and the EPSRC (EP/K005499/1).

PY - 2016/10/5

Y1 - 2016/10/5

N2 - The topology of coordination polymers containing 5-alkoxy isophthalic acids and first row transition metals was found to be dependent on the combination of solvent system used and length of the alkyl chain. Four different framework types were identified: Phase A, M6(ROip)5(OH)2(H2O)4·xH2O (M = Co and R = Et, Pr, or nBu, or M = Zn and R = Et); Phase B, M2(ROip)2(H2O) (M = Co or Zn and R = Et, Pr, nBu, or iBu, or M = Mn and R = nBu or iBu); Phase C, Zn3(EtOip)2(OH)2; and Phase D, Zn2(EtOip)2(H2O)3. Preliminary screening of the NO storage and release capabilities of the Co-containing materials is also reported.

AB - The topology of coordination polymers containing 5-alkoxy isophthalic acids and first row transition metals was found to be dependent on the combination of solvent system used and length of the alkyl chain. Four different framework types were identified: Phase A, M6(ROip)5(OH)2(H2O)4·xH2O (M = Co and R = Et, Pr, or nBu, or M = Zn and R = Et); Phase B, M2(ROip)2(H2O) (M = Co or Zn and R = Et, Pr, nBu, or iBu, or M = Mn and R = nBu or iBu); Phase C, Zn3(EtOip)2(OH)2; and Phase D, Zn2(EtOip)2(H2O)3. Preliminary screening of the NO storage and release capabilities of the Co-containing materials is also reported.

U2 - 10.1021/acs.cgd.6b00853

DO - 10.1021/acs.cgd.6b00853

M3 - Article

SN - 1528-7483

VL - 16

SP - 5771

EP - 5780

JO - Crystal Growth & Design

JF - Crystal Growth & Design

IS - 10

ER -

Coordination polymers of 5-alkoxy isophthalic acids

Abstract

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Projects

Hemilabile switchable metal-organic: Hemilabile and switchable metal-organic frameworks

Non-classic Crystal Growth: Non-classic Crystal Growth and New Catalysts

Datasets

Coordination polymers of 5-alkoxy isophthalic acids (dataset)

Cite this