Coordination Chemistry of a novel Diphosphine Ligand Containing a P-N-Si-N-P Backbone

Matthew L. Clarke; Alexandra Martha Zoya Slawin; John Derek Woollins

Coordination Chemistry of a novel Diphosphine Ligand Containing a P-N-Si-N-P Backbone

Research output: Other contribution

Abstract

A novel multifunctionalised diphosphine ligand containing a P-N-Si-N-P backbone ha, been prepared and studied. The ligand, Ph2PN(Py)Si(Me)(2)N(Py)PPh2 from complexes with platinum and palladium containing six membered M-P-N-Si-N-P heterocycles. The structure, synthesis, and reactivity of these heterocycles is discussed.

Original language	English
Volume	168
Publication status	Published - 2001

Keywords

phosphine
bidentate
inorganic rings
TRANSITION-METAL CHEMISTRY
MAIN-GROUP HYDRAZIDES
COORDINATION CHEMISTRY
BIS(DIPHENYLPHOSPHINO)AMINE
COMPLEXES

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title = "Coordination Chemistry of a novel Diphosphine Ligand Containing a P-N-Si-N-P Backbone",

abstract = "A novel multifunctionalised diphosphine ligand containing a P-N-Si-N-P backbone ha, been prepared and studied. The ligand, Ph2PN(Py)Si(Me)(2)N(Py)PPh2 from complexes with platinum and palladium containing six membered M-P-N-Si-N-P heterocycles. The structure, synthesis, and reactivity of these heterocycles is discussed.",

keywords = "phosphine, bidentate, inorganic rings, TRANSITION-METAL CHEMISTRY, MAIN-GROUP HYDRAZIDES, COORDINATION CHEMISTRY, BIS(DIPHENYLPHOSPHINO)AMINE, COMPLEXES",

author = "Clarke, \{Matthew L.\} and Slawin, \{Alexandra Martha Zoya\} and Woollins, \{John Derek\}",

note = "Phosphorus, Sulf.Silicon",

year = "2001",

language = "English",

volume = "168",

type = "Other",

}

TY - GEN

T1 - Coordination Chemistry of a novel Diphosphine Ligand Containing a P-N-Si-N-P Backbone

AU - Clarke, Matthew L.

AU - Slawin, Alexandra Martha Zoya

AU - Woollins, John Derek

N1 - Phosphorus, Sulf.Silicon

PY - 2001

Y1 - 2001

N2 - A novel multifunctionalised diphosphine ligand containing a P-N-Si-N-P backbone ha, been prepared and studied. The ligand, Ph2PN(Py)Si(Me)(2)N(Py)PPh2 from complexes with platinum and palladium containing six membered M-P-N-Si-N-P heterocycles. The structure, synthesis, and reactivity of these heterocycles is discussed.

AB - A novel multifunctionalised diphosphine ligand containing a P-N-Si-N-P backbone ha, been prepared and studied. The ligand, Ph2PN(Py)Si(Me)(2)N(Py)PPh2 from complexes with platinum and palladium containing six membered M-P-N-Si-N-P heterocycles. The structure, synthesis, and reactivity of these heterocycles is discussed.

KW - phosphine

KW - bidentate

KW - inorganic rings

KW - TRANSITION-METAL CHEMISTRY

KW - MAIN-GROUP HYDRAZIDES

KW - COORDINATION CHEMISTRY

KW - BIS(DIPHENYLPHOSPHINO)AMINE

KW - COMPLEXES

M3 - Other contribution

VL - 168

ER -

Coordination Chemistry of a novel Diphosphine Ligand Containing a P-N-Si-N-P Backbone

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Keywords

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