Abstract
[GRAPHICS]
A Pd(OAc)(2)/diazabutadiene system has been developed for the catalytic cross-coupling of aryl halides with arylboronic acids. A combination of the diazabutadiene DAB-Cy (1, N,N'-dicyclohexyl-1,4-dizabutadiene) and Pd(OAc)(2) was found to form an excellent catalyst for the Suzuki-Miyaura cross-coupling of various aryl bromides and activated aryl chlorides with arylboronic acids.
Original language | English |
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Pages (from-to) | 1077-1080 |
Number of pages | 4 |
Journal | Organic Letters |
Volume | 3 |
Issue number | 7 |
Publication status | Published - 5 Apr 2001 |
Keywords
- N-HETEROCYCLIC CARBENES
- ALPHA-DIIMINE
- HECK REACTION
- COMPLEXES
- ARYL
- POLYMERIZATION
- CHLORIDES
- LIGANDS
- OLEFINS
- HALIDES