Convenient and efficient cross-coupling of aryl halides mediated by palladium/bulky nucleophilic carbenes and related ligands

L  Jafarpour; G A  Grasa; M S  Viciu; A C  Hillier; Steven Patrick Nolan

Convenient and efficient cross-coupling of aryl halides mediated by palladium/bulky nucleophilic carbenes and related ligands

L Jafarpour, G A Grasa, M S Viciu, A C Hillier, Steven Patrick Nolan

Research output: Contribution to journal › Article › peer-review

Abstract

Simple protocols are described for palladium-mediated C-C and C-N bond forming reactions. N-heterocyclic nucleophilic carbene ligands assist these transformations very effectively and allow for the use of the inexpensive arylchlorides as coupling partners. These non-phosphine palladium systems also permit simple workup procedures.

Original language	English
Pages (from-to)	10-16
Number of pages	7
Journal	Chimica Oggi-Chemistry Today
Volume	19
Issue number	7-8
Publication status	Published - 2001

Keywords

N-HETEROCYCLIC CARBENES
CATALYZED AMINATION
ARYLBORONIC ACIDS
GRIGNARD-REAGENTS
ORGANIC HALIDES
ALPHA-DIIMINE
METAL-COMPLEXES
GENERAL-METHOD
BOND FORMATION
VINYL HALIDES

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@article{32e8373856ba461bb41f5d1066ea7cb4,

title = "Convenient and efficient cross-coupling of aryl halides mediated by palladium/bulky nucleophilic carbenes and related ligands",

abstract = "Simple protocols are described for palladium-mediated C-C and C-N bond forming reactions. N-heterocyclic nucleophilic carbene ligands assist these transformations very effectively and allow for the use of the inexpensive arylchlorides as coupling partners. These non-phosphine palladium systems also permit simple workup procedures.",

keywords = "N-HETEROCYCLIC CARBENES, CATALYZED AMINATION, ARYLBORONIC ACIDS, GRIGNARD-REAGENTS, ORGANIC HALIDES, ALPHA-DIIMINE, METAL-COMPLEXES, GENERAL-METHOD, BOND FORMATION, VINYL HALIDES",

author = "L Jafarpour and Grasa, {G A} and Viciu, {M S} and Hillier, {A C} and Nolan, {Steven Patrick}",

year = "2001",

language = "English",

volume = "19",

pages = "10--16",

journal = "Chimica Oggi-Chemistry Today",

issn = "0392-839X",

publisher = "TeknoScienze",

number = "7-8",

}

TY - JOUR

T1 - Convenient and efficient cross-coupling of aryl halides mediated by palladium/bulky nucleophilic carbenes and related ligands

AU - Jafarpour, L

AU - Grasa, G A

AU - Viciu, M S

AU - Hillier, A C

AU - Nolan, Steven Patrick

PY - 2001

Y1 - 2001

N2 - Simple protocols are described for palladium-mediated C-C and C-N bond forming reactions. N-heterocyclic nucleophilic carbene ligands assist these transformations very effectively and allow for the use of the inexpensive arylchlorides as coupling partners. These non-phosphine palladium systems also permit simple workup procedures.

AB - Simple protocols are described for palladium-mediated C-C and C-N bond forming reactions. N-heterocyclic nucleophilic carbene ligands assist these transformations very effectively and allow for the use of the inexpensive arylchlorides as coupling partners. These non-phosphine palladium systems also permit simple workup procedures.

KW - N-HETEROCYCLIC CARBENES

KW - CATALYZED AMINATION

KW - ARYLBORONIC ACIDS

KW - GRIGNARD-REAGENTS

KW - ORGANIC HALIDES

KW - ALPHA-DIIMINE

KW - METAL-COMPLEXES

KW - GENERAL-METHOD

KW - BOND FORMATION

KW - VINYL HALIDES

M3 - Article

SN - 0392-839X

VL - 19

SP - 10

EP - 16

JO - Chimica Oggi-Chemistry Today

JF - Chimica Oggi-Chemistry Today

IS - 7-8

ER -

Convenient and efficient cross-coupling of aryl halides mediated by palladium/bulky nucleophilic carbenes and related ligands

Abstract

Keywords

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