Convenient and efficient cross-coupling of aryl halides mediated by palladium/bulky nucleophilic carbenes and related ligands

L Jafarpour, G A Grasa, M S Viciu, A C Hillier, Steven Patrick Nolan

Research output: Contribution to journalArticlepeer-review

3 Citations (Scopus)

Abstract

Simple protocols are described for palladium-mediated C-C and C-N bond forming reactions. N-heterocyclic nucleophilic carbene ligands assist these transformations very effectively and allow for the use of the inexpensive arylchlorides as coupling partners. These non-phosphine palladium systems also permit simple workup procedures.

Original languageEnglish
Pages (from-to)10-16
Number of pages7
JournalChimica Oggi-Chemistry Today
Volume19
Issue number7-8
Publication statusPublished - 2001

Keywords

  • N-HETEROCYCLIC CARBENES
  • CATALYZED AMINATION
  • ARYLBORONIC ACIDS
  • GRIGNARD-REAGENTS
  • ORGANIC HALIDES
  • ALPHA-DIIMINE
  • METAL-COMPLEXES
  • GENERAL-METHOD
  • BOND FORMATION
  • VINYL HALIDES

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