Control of polymer-electrode interactions: the effect of leaving group on the optical properties and device characteristics of EHPPV

SC Lo; LO Palsson; M Kilitziraki; PL Burn; Ifor David William Samuel

Control of polymer-electrode interactions: the effect of leaving group on the optical properties and device characteristics of EHPPV

SC Lo, LO Palsson, M Kilitziraki, PL Burn, Ifor David William Samuel

Research output: Contribution to journal › Article › peer-review

27 Citations (Scopus)

Abstract

poly[2-(2'-ethylhexyloxy)-1,4-phenylenevinylene] (EHPPV) was prepared via chloro, S-methyl xanthate and O-ethyl xanthate precursor polymers. The choice of leaving group used was found to control the optical and device properties of the EHPPV with the variations arising from the differing chemical interactions of the leaving groups with indium tin oxide (ITO). The leaving group-ITO interactions were found to dominate the properties of EHPPV when formed from the commonly used chloro precursor polymer and this problem could be solved by use of xanthate leaving groups which were found not to react with the contact.

Original language	English
Pages (from-to)	2228
Number of pages	2228
Journal	Journal of Materials Chemistry
Volume	11
Publication status	Published - 2001

Keywords

LIGHT-EMITTING-DIODES
POLY(P-PHENYLENE VINYLENE)
CONJUGATED POLYMERS
PRECURSOR
ROUTE
CHEMISTRY
PPVS

Cite this

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title = "Control of polymer-electrode interactions: the effect of leaving group on the optical properties and device characteristics of EHPPV",

abstract = "poly[2-(2'-ethylhexyloxy)-1,4-phenylenevinylene] (EHPPV) was prepared via chloro, S-methyl xanthate and O-ethyl xanthate precursor polymers. The choice of leaving group used was found to control the optical and device properties of the EHPPV with the variations arising from the differing chemical interactions of the leaving groups with indium tin oxide (ITO). The leaving group-ITO interactions were found to dominate the properties of EHPPV when formed from the commonly used chloro precursor polymer and this problem could be solved by use of xanthate leaving groups which were found not to react with the contact.",

keywords = "LIGHT-EMITTING-DIODES, POLY(P-PHENYLENE VINYLENE), CONJUGATED POLYMERS, PRECURSOR, ROUTE, CHEMISTRY, PPVS",

author = "SC Lo and LO Palsson and M Kilitziraki and PL Burn and Samuel, {Ifor David William}",

year = "2001",

language = "English",

volume = "11",

pages = "2228",

journal = "Journal of Materials Chemistry",

issn = "0959-9428",

publisher = "Royal Society of Chemistry",

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TY - JOUR

T1 - Control of polymer-electrode interactions: the effect of leaving group on the optical properties and device characteristics of EHPPV

AU - Lo, SC

AU - Palsson, LO

AU - Kilitziraki, M

AU - Burn, PL

AU - Samuel, Ifor David William

PY - 2001

Y1 - 2001

N2 - poly[2-(2'-ethylhexyloxy)-1,4-phenylenevinylene] (EHPPV) was prepared via chloro, S-methyl xanthate and O-ethyl xanthate precursor polymers. The choice of leaving group used was found to control the optical and device properties of the EHPPV with the variations arising from the differing chemical interactions of the leaving groups with indium tin oxide (ITO). The leaving group-ITO interactions were found to dominate the properties of EHPPV when formed from the commonly used chloro precursor polymer and this problem could be solved by use of xanthate leaving groups which were found not to react with the contact.

AB - poly[2-(2'-ethylhexyloxy)-1,4-phenylenevinylene] (EHPPV) was prepared via chloro, S-methyl xanthate and O-ethyl xanthate precursor polymers. The choice of leaving group used was found to control the optical and device properties of the EHPPV with the variations arising from the differing chemical interactions of the leaving groups with indium tin oxide (ITO). The leaving group-ITO interactions were found to dominate the properties of EHPPV when formed from the commonly used chloro precursor polymer and this problem could be solved by use of xanthate leaving groups which were found not to react with the contact.

KW - LIGHT-EMITTING-DIODES

KW - POLY(P-PHENYLENE VINYLENE)

KW - CONJUGATED POLYMERS

KW - PRECURSOR

KW - ROUTE

KW - CHEMISTRY

KW - PPVS

UR - http://www.scopus.com/inward/record.url?scp=0034847247&partnerID=8YFLogxK

M3 - Article

SN - 0959-9428

VL - 11

SP - 2228

JO - Journal of Materials Chemistry

JF - Journal of Materials Chemistry

ER -

Control of polymer-electrode interactions: the effect of leaving group on the optical properties and device characteristics of EHPPV

Abstract

Keywords

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