Continuous flow knitting of a triptycene hypercrosslinked polymer

Cher Hon Lau; Tian-dan Lu; Shi-Peng Sun; Xianfeng Chen; Mariolino Carta; Daniel M. Dawson

doi:10.1039/C9CC03731D

Continuous flow knitting of a triptycene hypercrosslinked polymer

Cher Hon Lau, Tian-dan Lu, Shi-Peng Sun, Xianfeng Chen, Mariolino Carta, Daniel M. Dawson

Research output: Contribution to journal › Article › peer-review

Abstract

By replacing Lewis acids with Brønsted acids as catalysts, continuous flow synthesis of hypercrosslinked polymers is achieved within 10% of the time required for a typical batch reaction. Compared with batch-synthesised polymers, the flow-produced materials take up 24% more CO₂, precluding the need for lengthy reaction protocols to yield high-performance hypercrosslinked polymers for carbon capture.

Original language	English
Pages (from-to)	8571-8574
Number of pages	4
Journal	Chemical Communications
Volume	55
Issue number	59
Early online date	27 Jun 2019
DOIs	https://doi.org/10.1039/C9CC03731D
Publication status	Published - 28 Jul 2019

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10.1039/C9CC03731DLicence: CC BY-NC

Lau_2019_CC_Flowknitting_CC
Copyright © 2019 The Author(s). Open Access Article. This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.
Final published version, 2.85 MBLicence: CC BY-NC

Cite this

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title = "Continuous flow knitting of a triptycene hypercrosslinked polymer",

abstract = "By replacing Lewis acids with Br{\o}nsted acids as catalysts, continuous flow synthesis of hypercrosslinked polymers is achieved within 10% of the time required for a typical batch reaction. Compared with batch-synthesised polymers, the flow-produced materials take up 24% more CO2, precluding the need for lengthy reaction protocols to yield high-performance hypercrosslinked polymers for carbon capture.",

author = "Lau, {Cher Hon} and Tian-dan Lu and Shi-Peng Sun and Xianfeng Chen and Mariolino Carta and Dawson, {Daniel M.}",

note = "The authors are grateful for the support of The University of Edinburgh Chancellor Fellowship Scheme and State Key Laboratory for Membrane Separations, China (NTU-KL17-03).",

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AU - Lau, Cher Hon

AU - Lu, Tian-dan

AU - Sun, Shi-Peng

AU - Chen, Xianfeng

AU - Carta, Mariolino

AU - Dawson, Daniel M.

N1 - The authors are grateful for the support of The University of Edinburgh Chancellor Fellowship Scheme and State Key Laboratory for Membrane Separations, China (NTU-KL17-03).

PY - 2019/7/28

Y1 - 2019/7/28

N2 - By replacing Lewis acids with Brønsted acids as catalysts, continuous flow synthesis of hypercrosslinked polymers is achieved within 10% of the time required for a typical batch reaction. Compared with batch-synthesised polymers, the flow-produced materials take up 24% more CO2, precluding the need for lengthy reaction protocols to yield high-performance hypercrosslinked polymers for carbon capture.

AB - By replacing Lewis acids with Brønsted acids as catalysts, continuous flow synthesis of hypercrosslinked polymers is achieved within 10% of the time required for a typical batch reaction. Compared with batch-synthesised polymers, the flow-produced materials take up 24% more CO2, precluding the need for lengthy reaction protocols to yield high-performance hypercrosslinked polymers for carbon capture.

U2 - 10.1039/C9CC03731D

DO - 10.1039/C9CC03731D

M3 - Article

SN - 1359-7345

VL - 55

SP - 8571

EP - 8574

JO - Chemical Communications

JF - Chemical Communications

IS - 59

ER -

Continuous flow knitting of a triptycene hypercrosslinked polymer

Abstract

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