Continuous flow homogeneous catalysis: hydroformylation of alkenes in supercritical fluid-ionic liquid biphasic mixtures

MF Sellin; PB Webb; David John Cole-Hamilton

Continuous flow homogeneous catalysis: hydroformylation of alkenes in supercritical fluid-ionic liquid biphasic mixtures

MF Sellin, PB Webb, David John Cole-Hamilton

Research output: Other contribution

252 Citations (Scopus)

Abstract

Rhodium complexes of [1-propyl-3-methylimidazolium](2) [PhP(C6H4SO3-3)(2)] dissolved in the ionic liquid, 1-butyl-3-methylimidazolium hexafluorophosphate catalyse the hydroformylation of oct-1-ene at a constant rate for > 20 h in a continuous flow process in which the substrate, gases and products are transported in and out of the reactor dissolved in scCO(2); <1 ppm rhodium is present in the collected product.

Original language	English
Publication status	Published - 2001

Keywords

RHODIUM
COMPLEXES
SOLVENTS
CO2

Cite this

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title = "Continuous flow homogeneous catalysis: hydroformylation of alkenes in supercritical fluid-ionic liquid biphasic mixtures",

abstract = "Rhodium complexes of [1-propyl-3-methylimidazolium](2) [PhP(C6H4SO3-3)(2)] dissolved in the ionic liquid, 1-butyl-3-methylimidazolium hexafluorophosphate catalyse the hydroformylation of oct-1-ene at a constant rate for > 20 h in a continuous flow process in which the substrate, gases and products are transported in and out of the reactor dissolved in scCO(2); <1 ppm rhodium is present in the collected product.",

keywords = "RHODIUM, COMPLEXES, SOLVENTS, CO2",

author = "MF Sellin and PB Webb and Cole-Hamilton, {David John}",

note = "Chem Commun",

year = "2001",

language = "English",

type = "Other",

}

TY - GEN

T1 - Continuous flow homogeneous catalysis: hydroformylation of alkenes in supercritical fluid-ionic liquid biphasic mixtures

AU - Sellin, MF

AU - Webb, PB

AU - Cole-Hamilton, David John

N1 - Chem Commun

PY - 2001

Y1 - 2001

N2 - Rhodium complexes of [1-propyl-3-methylimidazolium](2) [PhP(C6H4SO3-3)(2)] dissolved in the ionic liquid, 1-butyl-3-methylimidazolium hexafluorophosphate catalyse the hydroformylation of oct-1-ene at a constant rate for > 20 h in a continuous flow process in which the substrate, gases and products are transported in and out of the reactor dissolved in scCO(2); <1 ppm rhodium is present in the collected product.

AB - Rhodium complexes of [1-propyl-3-methylimidazolium](2) [PhP(C6H4SO3-3)(2)] dissolved in the ionic liquid, 1-butyl-3-methylimidazolium hexafluorophosphate catalyse the hydroformylation of oct-1-ene at a constant rate for > 20 h in a continuous flow process in which the substrate, gases and products are transported in and out of the reactor dissolved in scCO(2); <1 ppm rhodium is present in the collected product.

KW - RHODIUM

KW - COMPLEXES

KW - SOLVENTS

KW - CO2

UR - http://www.scopus.com/inward/record.url?scp=0035926109&partnerID=8YFLogxK

M3 - Other contribution

ER -

Continuous flow homogeneous catalysis: hydroformylation of alkenes in supercritical fluid-ionic liquid biphasic mixtures

Abstract

Keywords

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