Constructing cerium supramolecular wheels and encapsulating uranium with a Schiff-base calixpyrrole ligand

Polly L. Arnold; Natalie A. Potter (nee Jones); Christopher D. Carmichael; Alexandra M. Z. Slawin; Paul Roussel; Jason B. Love

doi:10.1039/b921132b

Constructing cerium supramolecular wheels and encapsulating uranium with a Schiff-base calixpyrrole ligand

Polly L. Arnold, Natalie A. Potter (nee Jones), Christopher D. Carmichael, Alexandra M. Z. Slawin, Paul Roussel, Jason B. Love

Research output: Contribution to journal › Article › peer-review

Abstract

Trinuclear, supramolecular wheel structures are formed spontaneously from the metallation of a Schiff-base-pyrrole macrocycle by Ce3+ cations, while the related actinide U3+ cation is instead oxidised to U4+ and encapsulated by the macrocyclic framework.

Original language	English
Pages (from-to)	1833-1835
Number of pages	3
Journal	Chemical Communications
Volume	46
Issue number	11
DOIs	https://doi.org/10.1039/b921132b
Publication status	Published - 2010

Keywords

TETRAPYRROLE LIGANDS
CRYSTAL-STRUCTURE
LANTHANIDE IONS
COMPLEXES
MACROCYCLE
PORPHYRINS
STRATEGIES
MOLECULES
METAL
BI

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10.1039/b921132b

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@article{6276108930314dffabdbc323d9c10124,

title = "Constructing cerium supramolecular wheels and encapsulating uranium with a Schiff-base calixpyrrole ligand",

abstract = "Trinuclear, supramolecular wheel structures are formed spontaneously from the metallation of a Schiff-base-pyrrole macrocycle by Ce3+ cations, while the related actinide U3+ cation is instead oxidised to U4+ and encapsulated by the macrocyclic framework.",

keywords = "TETRAPYRROLE LIGANDS, CRYSTAL-STRUCTURE, LANTHANIDE IONS, COMPLEXES, MACROCYCLE, PORPHYRINS, STRATEGIES, MOLECULES, METAL, BI",

author = "Arnold, {Polly L.} and {Potter (nee Jones)}, {Natalie A.} and Carmichael, {Christopher D.} and Slawin, {Alexandra M. Z.} and Paul Roussel and Love, {Jason B.}",

year = "2010",

doi = "10.1039/b921132b",

language = "English",

volume = "46",

pages = "1833--1835",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "11",

}

TY - JOUR

T1 - Constructing cerium supramolecular wheels and encapsulating uranium with a Schiff-base calixpyrrole ligand

AU - Arnold, Polly L.

AU - Potter (nee Jones), Natalie A.

AU - Carmichael, Christopher D.

AU - Slawin, Alexandra M. Z.

AU - Roussel, Paul

AU - Love, Jason B.

PY - 2010

Y1 - 2010

N2 - Trinuclear, supramolecular wheel structures are formed spontaneously from the metallation of a Schiff-base-pyrrole macrocycle by Ce3+ cations, while the related actinide U3+ cation is instead oxidised to U4+ and encapsulated by the macrocyclic framework.

AB - Trinuclear, supramolecular wheel structures are formed spontaneously from the metallation of a Schiff-base-pyrrole macrocycle by Ce3+ cations, while the related actinide U3+ cation is instead oxidised to U4+ and encapsulated by the macrocyclic framework.

KW - TETRAPYRROLE LIGANDS

KW - CRYSTAL-STRUCTURE

KW - LANTHANIDE IONS

KW - COMPLEXES

KW - MACROCYCLE

KW - PORPHYRINS

KW - STRATEGIES

KW - MOLECULES

KW - METAL

KW - BI

U2 - 10.1039/b921132b

DO - 10.1039/b921132b

M3 - Article

SN - 1359-7345

VL - 46

SP - 1833

EP - 1835

JO - Chemical Communications

JF - Chemical Communications

IS - 11

ER -

Constructing cerium supramolecular wheels and encapsulating uranium with a Schiff-base calixpyrrole ligand

Abstract

Keywords

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