Conformational control in PtS2(PR2)2N metallacycles via ligand-substituent effects (R = Ph or OPh)

J R  PHILLIPS; A M Z  SLAWIN; A J P  WHITE; D J  WILLIAMS; J D  WOOLLINS

doi:10.1039/DT9950002467

Conformational control in PtS2(PR2)2N metallacycles via ligand-substituent effects (R = Ph or OPh)

J R PHILLIPS, A M Z SLAWIN, A J P WHITE, D J WILLIAMS, J D WOOLLINS

Research output: Contribution to journal › Comment/debate › peer-review

Abstract

Two complexes containing the PtS2(PR(2))(2)N ring [Pt{R'P-2(S)NP(S)R'(2)}(PR(3))(2)] PF6 (R = Et, R' = Ph; R = Me, R' = OPh), have been synthesised and structurally characterised: changing R from Ph to OPh has a dramatic effect on the ring conformation; whereas a complex with R = Ph has a puckered ring, for R = OPh the S-P-N-P-S portion of the ring is flat.

Original language	English
Pages (from-to)	2467-2468
Number of pages	2
Journal	Journal of the Chemical Society, Dalton Transactions
Issue number	14
DOIs	https://doi.org/10.1039/DT9950002467
Publication status	Published - 21 Jul 1995

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CRYSTAL

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10.1039/DT9950002467

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title = "Conformational control in PtS2(PR2)2N metallacycles via ligand-substituent effects (R = Ph or OPh)",

abstract = "Two complexes containing the PtS2(PR(2))(2)N ring [Pt\{R'P-2(S)NP(S)R'(2)\}(PR(3))(2)] PF6 (R = Et, R' = Ph; R = Me, R' = OPh), have been synthesised and structurally characterised: changing R from Ph to OPh has a dramatic effect on the ring conformation; whereas a complex with R = Ph has a puckered ring, for R = OPh the S-P-N-P-S portion of the ring is flat.",

keywords = "CRYSTAL",

author = "PHILLIPS, \{J R\} and SLAWIN, \{A M Z\} and WHITE, \{A J P\} and WILLIAMS, \{D J\} and WOOLLINS, \{J D\}",

year = "1995",

month = jul,

day = "21",

doi = "10.1039/DT9950002467",

language = "English",

pages = "2467--2468",

journal = "Journal of the Chemical Society, Dalton Transactions",

issn = "0300-9246",

publisher = "Royal Society of Chemistry",

number = "14",

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TY - JOUR

T1 - Conformational control in PtS2(PR2)2N metallacycles via ligand-substituent effects (R = Ph or OPh)

AU - PHILLIPS, J R

AU - SLAWIN, A M Z

AU - WHITE, A J P

AU - WILLIAMS, D J

AU - WOOLLINS, J D

PY - 1995/7/21

Y1 - 1995/7/21

N2 - Two complexes containing the PtS2(PR(2))(2)N ring [Pt{R'P-2(S)NP(S)R'(2)}(PR(3))(2)] PF6 (R = Et, R' = Ph; R = Me, R' = OPh), have been synthesised and structurally characterised: changing R from Ph to OPh has a dramatic effect on the ring conformation; whereas a complex with R = Ph has a puckered ring, for R = OPh the S-P-N-P-S portion of the ring is flat.

AB - Two complexes containing the PtS2(PR(2))(2)N ring [Pt{R'P-2(S)NP(S)R'(2)}(PR(3))(2)] PF6 (R = Et, R' = Ph; R = Me, R' = OPh), have been synthesised and structurally characterised: changing R from Ph to OPh has a dramatic effect on the ring conformation; whereas a complex with R = Ph has a puckered ring, for R = OPh the S-P-N-P-S portion of the ring is flat.

KW - CRYSTAL

UR - https://www.scopus.com/pages/publications/37049067612

U2 - 10.1039/DT9950002467

DO - 10.1039/DT9950002467

M3 - Comment/debate

SN - 0300-9246

SP - 2467

EP - 2468

JO - Journal of the Chemical Society, Dalton Transactions

JF - Journal of the Chemical Society, Dalton Transactions

IS - 14

ER -

Conformational control in PtS2(PR2)2N metallacycles via ligand-substituent effects (R = Ph or OPh)

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