Conformational control in PtS2(PR2)2N metallacycles via ligand-substituent effects (R = Ph or OPh)

J R PHILLIPS, A M Z SLAWIN, A J P WHITE, D J WILLIAMS, J D WOOLLINS

Research output: Contribution to journalComment/debatepeer-review

37 Citations (Scopus)

Abstract

Two complexes containing the PtS2(PR(2))(2)N ring [Pt{R'P-2(S)NP(S)R'(2)}(PR(3))(2)] PF6 (R = Et, R' = Ph; R = Me, R' = OPh), have been synthesised and structurally characterised: changing R from Ph to OPh has a dramatic effect on the ring conformation; whereas a complex with R = Ph has a puckered ring, for R = OPh the S-P-N-P-S portion of the ring is flat.

Original languageEnglish
Pages (from-to)2467-2468
Number of pages2
JournalJournal of the Chemical Society, Dalton Transactions
Issue number14
DOIs
Publication statusPublished - 21 Jul 1995

Keywords

  • CRYSTAL

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