Conducting olefin metathesis reactions in air: breaking the paradigm

Stefano Guidone; Olivier Songis; Fady Nahra; Catherine S.J. Cazin

doi:10.1021/acscatal.5b00197

Conducting olefin metathesis reactions in air: breaking the paradigm

Stefano Guidone, Olivier Songis, Fady Nahra, Catherine S.J. Cazin

Research output: Contribution to journal › Article › peer-review

Abstract

The first study of low catalyst loading olefin metathesis reactions in air is reported. TON values of up to 7000 were obtained using non-degassed solvents with commercially available pre-catalysts Caz-1, Hov-II and Ind-II. The simple experimental conditions allow olefin metathesis reactions to be carried out on the benchtop using technical grade solvents in air.

Original language	English
Pages (from-to)	2697-2701
Journal	ACS Catalysis
Volume	5
Early online date	25 Mar 2015
DOIs	https://doi.org/10.1021/acscatal.5b00197
Publication status	Published - 2015

Keywords

Olefin metathesis
Homogeneous catalysis
Ruthenium
Phosphite
Air

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10.1021/acscatal.5b00197

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This document is the Accepted Manuscript version of a Published Work that appeared in final form in ACS Catalysis, copyright © 2015 American Chemical Society, after peer review and technical editing by the publisher. To access the final edited and published work see http://pubs.acs.org/doi/abs/10.1021/acscatal.5b00197.
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title = "Conducting olefin metathesis reactions in air: breaking the paradigm",

abstract = "The first study of low catalyst loading olefin metathesis reactions in air is reported. TON values of up to 7000 were obtained using non-degassed solvents with commercially available pre-catalysts Caz-1, Hov-II and Ind-II. The simple experimental conditions allow olefin metathesis reactions to be carried out on the benchtop using technical grade solvents in air. ",

keywords = "Olefin metathesis, Homogeneous catalysis, Ruthenium, Phosphite, Air",

author = "Stefano Guidone and Olivier Songis and Fady Nahra and Cazin, \{Catherine S.J.\}",

note = "The authors gratefully acknowledge the Royal Society (University Research Fellowship to CSJC) and the EC (CP-FP 211468-2 EUMET) for funding. ",

year = "2015",

doi = "10.1021/acscatal.5b00197",

language = "English",

volume = "5",

pages = "2697--2701",

journal = "ACS Catalysis",

issn = "2155-5435",

publisher = "American Chemical Society (ACS)",

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TY - JOUR

T1 - Conducting olefin metathesis reactions in air

T2 - breaking the paradigm

AU - Guidone, Stefano

AU - Songis, Olivier

AU - Nahra, Fady

AU - Cazin, Catherine S.J.

N1 - The authors gratefully acknowledge the Royal Society (University Research Fellowship to CSJC) and the EC (CP-FP 211468-2 EUMET) for funding.

PY - 2015

Y1 - 2015

N2 - The first study of low catalyst loading olefin metathesis reactions in air is reported. TON values of up to 7000 were obtained using non-degassed solvents with commercially available pre-catalysts Caz-1, Hov-II and Ind-II. The simple experimental conditions allow olefin metathesis reactions to be carried out on the benchtop using technical grade solvents in air.

AB - The first study of low catalyst loading olefin metathesis reactions in air is reported. TON values of up to 7000 were obtained using non-degassed solvents with commercially available pre-catalysts Caz-1, Hov-II and Ind-II. The simple experimental conditions allow olefin metathesis reactions to be carried out on the benchtop using technical grade solvents in air.

KW - Olefin metathesis

KW - Homogeneous catalysis

KW - Ruthenium

KW - Phosphite

KW - Air

UR - http://pubs.acs.org/doi/suppl/10.1021/acscatal.5b00197

UR - https://www.scopus.com/pages/publications/84929485871

U2 - 10.1021/acscatal.5b00197

DO - 10.1021/acscatal.5b00197

M3 - Article

SN - 2155-5435

VL - 5

SP - 2697

EP - 2701

JO - ACS Catalysis

JF - ACS Catalysis

ER -

Conducting olefin metathesis reactions in air: breaking the paradigm

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Keywords

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Catalytic C-H bond functionalisation: Catalytic C-H bond functionalisation

EUMET: EU FP7 'EUMET' Olefin Metathesis as a Practical Synthetic Tool

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Conducting olefin metathesis reactions in air: breaking the paradigm

Abstract

Keywords

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Catalytic C-H bond functionalisation: Catalytic C-H bond functionalisation

EUMET: EU FP7 'EUMET' Olefin Metathesis as a Practical Synthetic Tool

Cite this