Conducting olefin metathesis reactions in air: breaking the paradigm

Stefano Guidone, Olivier Songis, Fady Nahra, Catherine S.J. Cazin

Research output: Contribution to journalArticlepeer-review

46 Citations (Scopus)
4 Downloads (Pure)

Abstract

The first study of low catalyst loading olefin metathesis reactions in air is reported. TON values of up to 7000 were obtained using non-degassed solvents with commercially available pre-catalysts Caz-1, Hov-II and Ind-II. The simple experimental conditions allow olefin metathesis reactions to be carried out on the benchtop using technical grade solvents in air.
Original languageEnglish
Pages (from-to)2697-2701
JournalACS Catalysis
Volume5
Early online date25 Mar 2015
DOIs
Publication statusPublished - 2015

Keywords

  • Olefin metathesis
  • Homogeneous catalysis
  • Ruthenium
  • Phosphite
  • Air

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