Abstract
An exact analytical expression for the condensation energy Econd(T) of a phonon-driven superconductor for all absolute temperatures T and for any coupling strength is introduced so as to calculate the Helmholtz free energy difference Fs(T) - Fn(T) between superconducting (s) and normal (n) states. This is achieved via a boson–fermion ternary gas theory—called the generalized Bose–Einstein condensation (GBEC) theory—which includes two-hole Cooper pairs, two-electron ones as well as single, free/unbound electrons. The GBEC formalism turns out to be quite useful in dealing with nonzero T values of Econd(T) and reproduces several well-known experimental results. An expression for the condensation energy per atom is also calculated and applied to aluminum and niobium, and both results are compared with experimental data.
Original language | English |
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Journal | Journal of Low Temperature Physics |
Volume | First Online |
DOIs | |
Publication status | Published - 29 Aug 2020 |
Keywords
- BCS theory
- Condensation energy
- Generalized Bose–Einstein condensation (GBEC) theory
- Two-electron and two-hole Cooper pairs