Comparison of N-(3,4,5-trimethoxybenzylidene)naphthalen-1-amine and its reduction product N-(3,4,5-trimethoxybenzyl)naphthalen-1-amine

A. Garay, R. Abonía, J. Cobo, C. Glidewell

Research output: Contribution to journalArticlepeer-review

1 Citation (Scopus)
1 Downloads (Pure)

Abstract

The molecules in (E)-N-(3,4,5-trimethoxybenzylidene)naphthalen-1-amine, C20H21NO3, (I), and its reduction product N-(3,4,5-trimethoxybenzyl)naphthalen-1-amine, C20H19NO3, (II), are both conformationally chiral, but (I) crystallizes in a centrosymmetric space group, while (II) crystallizes with just one conformational enantiomer in each crystal. A combination of two C - H⋯O hydrogen bonds links the molecules of (I) into sheets containing a single type of R66(44) ring, and these sheets are linked into a continuous three-dimensional array by a single π-π stacking interaction. The molecules of (II) are linked into complex sheets by a combination of N - H⋯O, C - H⋯O and C - H⋯π(arene) hydrogen bonds.

Original languageEnglish
Pages (from-to)210-215
Number of pages6
JournalActa Crystallographica Section C: Crystal Structure Communications
Volume70
Issue number2
DOIs
Publication statusPublished - 1 Feb 2014

Keywords

  • Crystal structure
  • Supra­molecular structure
  • Hydrogen bonding

Fingerprint

Dive into the research topics of 'Comparison of N-(3,4,5-trimethoxybenzylidene)naphthalen-1-amine and its reduction product N-(3,4,5-trimethoxybenzyl)naphthalen-1-amine'. Together they form a unique fingerprint.

Cite this