Combined QuEXAFS-XRD: A new technique in high-temperature materials chemistry. An illustrative in situ study of the zinc oxide-enhanced solid-state production of cordierite from a precursor zeolite

Gopinathan Sankar; Paul A. Wright; Srinivasan Natarajan; John Meurig Thomas; G. Neville Greaves; Andrew J. Dent; Barry R. Dobson; Christine A. Ramsdale; Richard H. Jones

doi:10.1021/j100140a002

Combined QuEXAFS-XRD: A new technique in high-temperature materials chemistry. An illustrative in situ study of the zinc oxide-enhanced solid-state production of cordierite from a precursor zeolite

Gopinathan Sankar
, Paul A. Wright
, Srinivasan Natarajan
, John Meurig Thomas^*
, G. Neville Greaves
, Andrew J. Dent
, Barry R. Dobson
, Christine A. Ramsdale
, Richard H. Jones

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

The power of combined quick EXAFS (QuEXAFS) and X-ray diffraction as a structural and kinetic tool in high-temperature solid-state chemistry is exemplified by the study of the conversion of Mg²⁺-exchanged zeolite B to cordierite, a process facilitated by trace amounts of zinc oxide. With a setup consisting of a position-sensitive detector and a rapidly scanning monochromator, time-resolved studies of short-range and long-range order within samples held in excess of 1000°C are routinely possible.

Original language	English
Pages (from-to)	9550-9554
Number of pages	5
Journal	Journal of Physical Chemistry
Volume	97
Issue number	38
DOIs	https://doi.org/10.1021/j100140a002
Publication status	Published - 1 Jan 1993

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Sankar, G., Wright, P. A., Natarajan, S., Thomas, J. M., Greaves, G. N., Dent, A. J., Dobson, B. R., Ramsdale, C. A., & Jones, R. H. (1993). Combined QuEXAFS-XRD: A new technique in high-temperature materials chemistry. An illustrative in situ study of the zinc oxide-enhanced solid-state production of cordierite from a precursor zeolite. Journal of Physical Chemistry, 97(38), 9550-9554. https://doi.org/10.1021/j100140a002

@article{012e06b40b3444e2a05f2c52cc54f157,

title = "Combined QuEXAFS-XRD: A new technique in high-temperature materials chemistry. An illustrative in situ study of the zinc oxide-enhanced solid-state production of cordierite from a precursor zeolite",

abstract = "The power of combined quick EXAFS (QuEXAFS) and X-ray diffraction as a structural and kinetic tool in high-temperature solid-state chemistry is exemplified by the study of the conversion of Mg2+-exchanged zeolite B to cordierite, a process facilitated by trace amounts of zinc oxide. With a setup consisting of a position-sensitive detector and a rapidly scanning monochromator, time-resolved studies of short-range and long-range order within samples held in excess of 1000°C are routinely possible.",

author = "Gopinathan Sankar and Wright, \{Paul A.\} and Srinivasan Natarajan and Thomas, \{John Meurig\} and Greaves, \{G. Neville\} and Dent, \{Andrew J.\} and Dobson, \{Barry R.\} and Ramsdale, \{Christine A.\} and Jones, \{Richard H.\}",

year = "1993",

month = jan,

day = "1",

doi = "10.1021/j100140a002",

language = "English",

volume = "97",

pages = "9550--9554",

journal = "Journal of Physical Chemistry",

issn = "0022-3654",

publisher = "American Chemical Society (ACS)",

number = "38",

}

Sankar, G, Wright, PA, Natarajan, S, Thomas, JM, Greaves, GN, Dent, AJ, Dobson, BR, Ramsdale, CA & Jones, RH 1993, 'Combined QuEXAFS-XRD: A new technique in high-temperature materials chemistry. An illustrative in situ study of the zinc oxide-enhanced solid-state production of cordierite from a precursor zeolite', Journal of Physical Chemistry, vol. 97, no. 38, pp. 9550-9554. https://doi.org/10.1021/j100140a002

Combined QuEXAFS-XRD: A new technique in high-temperature materials chemistry. An illustrative in situ study of the zinc oxide-enhanced solid-state production of cordierite from a precursor zeolite. / Sankar, Gopinathan; Wright, Paul A.; Natarajan, Srinivasan et al.
In: Journal of Physical Chemistry, Vol. 97, No. 38, 01.01.1993, p. 9550-9554.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Combined QuEXAFS-XRD

T2 - A new technique in high-temperature materials chemistry. An illustrative in situ study of the zinc oxide-enhanced solid-state production of cordierite from a precursor zeolite

AU - Sankar, Gopinathan

AU - Wright, Paul A.

AU - Natarajan, Srinivasan

AU - Thomas, John Meurig

AU - Greaves, G. Neville

AU - Dent, Andrew J.

AU - Dobson, Barry R.

AU - Ramsdale, Christine A.

AU - Jones, Richard H.

PY - 1993/1/1

Y1 - 1993/1/1

N2 - The power of combined quick EXAFS (QuEXAFS) and X-ray diffraction as a structural and kinetic tool in high-temperature solid-state chemistry is exemplified by the study of the conversion of Mg2+-exchanged zeolite B to cordierite, a process facilitated by trace amounts of zinc oxide. With a setup consisting of a position-sensitive detector and a rapidly scanning monochromator, time-resolved studies of short-range and long-range order within samples held in excess of 1000°C are routinely possible.

AB - The power of combined quick EXAFS (QuEXAFS) and X-ray diffraction as a structural and kinetic tool in high-temperature solid-state chemistry is exemplified by the study of the conversion of Mg2+-exchanged zeolite B to cordierite, a process facilitated by trace amounts of zinc oxide. With a setup consisting of a position-sensitive detector and a rapidly scanning monochromator, time-resolved studies of short-range and long-range order within samples held in excess of 1000°C are routinely possible.

UR - https://www.scopus.com/pages/publications/0001456144

U2 - 10.1021/j100140a002

DO - 10.1021/j100140a002

M3 - Article

AN - SCOPUS:0001456144

SN - 0022-3654

VL - 97

SP - 9550

EP - 9554

JO - Journal of Physical Chemistry

JF - Journal of Physical Chemistry

IS - 38

ER -

Combined QuEXAFS-XRD: A new technique in high-temperature materials chemistry. An illustrative in situ study of the zinc oxide-enhanced solid-state production of cordierite from a precursor zeolite

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