Color and Brightness Tuning in Heteronuclear Lanthanide Terephthalate Coordination Polymers

Victor Haquin; Mael Etienne; Carole Daiguebonne; Stephane Freslon; Guillaume Calvez; Kevin Bernot; Laurent Le Polles; Sharon Elizabeth Ashbrook; Martin Mitchell; Jean-Claude Buenzli; Svetlana V. Eliseeva; Olivier Guillou

doi:10.1002/ejic.201300381

Color and Brightness Tuning in Heteronuclear Lanthanide Terephthalate Coordination Polymers

Victor Haquin, Mael Etienne, Carole Daiguebonne, Stephane Freslon, Guillaume Calvez, Kevin Bernot, Laurent Le Polles^*, Sharon Elizabeth Ashbrook, Martin Mitchell, Jean-Claude Buenzli, Svetlana V. Eliseeva, Olivier Guillou

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

Heteronuclear lanthanide terephthalate coordination polymers with the general chemical formula [Ln2-2xLn2x(bdc)3(H2O)4], for which bdc2- symbolizes benzene-1,4-dicarboxylate (or terephthalate) and Ln and Ln represent trivalent rare earth ions, were synthesized and structurally characterized. Analysis of the Y/Lu compounds by 89Y and 13C solid-state NMR spectroscopy was carried out, and the results support the hypothesis of randomly distributed lanthanide ions. The spectroscopic and colorimetric properties of this family of compounds were investigated in detail. The resulting data demonstrate that this series of compounds presents highly tunable luminescence properties and clearly indicate that intermetallic deactivation processes play an important role in the emission mechanism. Playing with intermetallic distances allows one to tune the color and the brightness of the lanthanide emission in these coordination polymers.

Original language	English
Pages (from-to)	3464-3476
Number of pages	13
Journal	European Journal of Inorganic Chemistry
Volume	2013
Issue number	20
DOIs	https://doi.org/10.1002/ejic.201300381
Publication status	Published - Jul 2013

Keywords

Lanthanides
Coordination polymers
Luminescence
Structure elucidation
METAL-ORGANIC FRAMEWORK
LUMINESCENT PROPERTIES
CRYSTAL-STRUCTURES
HYBRID MATERIALS
WHITE-LIGHT
SOFT ACIDS
COMPLEXES
LIGAND
NMR
DESIGN

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Haquin, V., Etienne, M., Daiguebonne, C., Freslon, S., Calvez, G., Bernot, K., Le Polles, L., Ashbrook, S. E., Mitchell, M., Buenzli, J.-C., Eliseeva, S. V., & Guillou, O. (2013). Color and Brightness Tuning in Heteronuclear Lanthanide Terephthalate Coordination Polymers. European Journal of Inorganic Chemistry, 2013(20), 3464-3476. https://doi.org/10.1002/ejic.201300381

@article{6d69a561ebab4281911b2577f56f7b03,

title = "Color and Brightness Tuning in Heteronuclear Lanthanide Terephthalate Coordination Polymers",

abstract = "Heteronuclear lanthanide terephthalate coordination polymers with the general chemical formula [Ln2-2xLn2x(bdc)3(H2O)4], for which bdc2- symbolizes benzene-1,4-dicarboxylate (or terephthalate) and Ln and Ln represent trivalent rare earth ions, were synthesized and structurally characterized. Analysis of the Y/Lu compounds by 89Y and 13C solid-state NMR spectroscopy was carried out, and the results support the hypothesis of randomly distributed lanthanide ions. The spectroscopic and colorimetric properties of this family of compounds were investigated in detail. The resulting data demonstrate that this series of compounds presents highly tunable luminescence properties and clearly indicate that intermetallic deactivation processes play an important role in the emission mechanism. Playing with intermetallic distances allows one to tune the color and the brightness of the lanthanide emission in these coordination polymers.",

keywords = "Lanthanides, Coordination polymers, Luminescence, Structure elucidation, METAL-ORGANIC FRAMEWORK, LUMINESCENT PROPERTIES, CRYSTAL-STRUCTURES, HYBRID MATERIALS, WHITE-LIGHT, SOFT ACIDS, COMPLEXES, LIGAND, NMR, DESIGN",

author = "Victor Haquin and Mael Etienne and Carole Daiguebonne and Stephane Freslon and Guillaume Calvez and Kevin Bernot and {Le Polles}, Laurent and Ashbrook, {Sharon Elizabeth} and Martin Mitchell and Jean-Claude Buenzli and Eliseeva, {Svetlana V.} and Olivier Guillou",

year = "2013",

month = jul,

doi = "10.1002/ejic.201300381",

language = "English",

volume = "2013",

pages = "3464--3476",

journal = "European Journal of Inorganic Chemistry",

issn = "1434-1948",

publisher = "Wiley-Blackwell",

number = "20",

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TY - JOUR

T1 - Color and Brightness Tuning in Heteronuclear Lanthanide Terephthalate Coordination Polymers

AU - Haquin, Victor

AU - Etienne, Mael

AU - Daiguebonne, Carole

AU - Freslon, Stephane

AU - Calvez, Guillaume

AU - Bernot, Kevin

AU - Le Polles, Laurent

AU - Ashbrook, Sharon Elizabeth

AU - Mitchell, Martin

AU - Buenzli, Jean-Claude

AU - Eliseeva, Svetlana V.

AU - Guillou, Olivier

PY - 2013/7

Y1 - 2013/7

N2 - Heteronuclear lanthanide terephthalate coordination polymers with the general chemical formula [Ln2-2xLn2x(bdc)3(H2O)4], for which bdc2- symbolizes benzene-1,4-dicarboxylate (or terephthalate) and Ln and Ln represent trivalent rare earth ions, were synthesized and structurally characterized. Analysis of the Y/Lu compounds by 89Y and 13C solid-state NMR spectroscopy was carried out, and the results support the hypothesis of randomly distributed lanthanide ions. The spectroscopic and colorimetric properties of this family of compounds were investigated in detail. The resulting data demonstrate that this series of compounds presents highly tunable luminescence properties and clearly indicate that intermetallic deactivation processes play an important role in the emission mechanism. Playing with intermetallic distances allows one to tune the color and the brightness of the lanthanide emission in these coordination polymers.

AB - Heteronuclear lanthanide terephthalate coordination polymers with the general chemical formula [Ln2-2xLn2x(bdc)3(H2O)4], for which bdc2- symbolizes benzene-1,4-dicarboxylate (or terephthalate) and Ln and Ln represent trivalent rare earth ions, were synthesized and structurally characterized. Analysis of the Y/Lu compounds by 89Y and 13C solid-state NMR spectroscopy was carried out, and the results support the hypothesis of randomly distributed lanthanide ions. The spectroscopic and colorimetric properties of this family of compounds were investigated in detail. The resulting data demonstrate that this series of compounds presents highly tunable luminescence properties and clearly indicate that intermetallic deactivation processes play an important role in the emission mechanism. Playing with intermetallic distances allows one to tune the color and the brightness of the lanthanide emission in these coordination polymers.

KW - Lanthanides

KW - Coordination polymers

KW - Luminescence

KW - Structure elucidation

KW - METAL-ORGANIC FRAMEWORK

KW - LUMINESCENT PROPERTIES

KW - CRYSTAL-STRUCTURES

KW - HYBRID MATERIALS

KW - WHITE-LIGHT

KW - SOFT ACIDS

KW - COMPLEXES

KW - LIGAND

KW - NMR

KW - DESIGN

U2 - 10.1002/ejic.201300381

DO - 10.1002/ejic.201300381

M3 - Article

SN - 1434-1948

VL - 2013

SP - 3464

EP - 3476

JO - European Journal of Inorganic Chemistry

JF - European Journal of Inorganic Chemistry

IS - 20

ER -

Color and Brightness Tuning in Heteronuclear Lanthanide Terephthalate Coordination Polymers

Abstract

Keywords

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