cis-Dichloridobis(dimethoxyphenylphosphine)palladium(II)

Alexandra M. Z. Slawin; Paul G. Waddell; J. Derek Woollins

doi:10.1107/S1600536810006471

cis-Dichloridobis(dimethoxyphenylphosphine)palladium(II)

Alexandra M. Z. Slawin, Paul G. Waddell, J. Derek Woollins

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Abstract

The title compound, [PdCl2(C8H11O2P)(2)], has a comparable structure to those of related palladium dichloride complexes containing trimethyl phosphinite and methyl diphenyl phosphinite. The Pd atom is located on a crystallographic twofold rotation axis: thus, there is just one half-molecule in the asymmetric unit. The structure is isomorphous with the platinum analogue cis-[PtCl2{P(OMe)(2)Ph}(2)].

Original language	English
Pages (from-to)	M321-U3739
Number of pages	9
Journal	Acta Crystallographica. Section E, Structure reports online
Volume	66
Issue number	3
DOIs	https://doi.org/10.1107/S1600536810006471
Publication status	Published - Mar 2010

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ActaCrystE66 m321
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title = "cis-Dichloridobis(dimethoxyphenylphosphine)palladium(II)",

abstract = "The title compound, [PdCl2(C8H11O2P)(2)], has a comparable structure to those of related palladium dichloride complexes containing trimethyl phosphinite and methyl diphenyl phosphinite. The Pd atom is located on a crystallographic twofold rotation axis: thus, there is just one half-molecule in the asymmetric unit. The structure is isomorphous with the platinum analogue cis-[PtCl2\{P(OMe)(2)Ph\}(2)].",

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AU - Slawin, Alexandra M. Z.

AU - Waddell, Paul G.

AU - Woollins, J. Derek

PY - 2010/3

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N2 - The title compound, [PdCl2(C8H11O2P)(2)], has a comparable structure to those of related palladium dichloride complexes containing trimethyl phosphinite and methyl diphenyl phosphinite. The Pd atom is located on a crystallographic twofold rotation axis: thus, there is just one half-molecule in the asymmetric unit. The structure is isomorphous with the platinum analogue cis-[PtCl2{P(OMe)(2)Ph}(2)].

AB - The title compound, [PdCl2(C8H11O2P)(2)], has a comparable structure to those of related palladium dichloride complexes containing trimethyl phosphinite and methyl diphenyl phosphinite. The Pd atom is located on a crystallographic twofold rotation axis: thus, there is just one half-molecule in the asymmetric unit. The structure is isomorphous with the platinum analogue cis-[PtCl2{P(OMe)(2)Ph}(2)].

UR - https://www.scopus.com/pages/publications/77949396450

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DO - 10.1107/S1600536810006471

M3 - Article

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JO - Acta Crystallographica. Section E, Structure reports online

JF - Acta Crystallographica. Section E, Structure reports online

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ER -

cis-Dichloridobis(dimethoxyphenylphosphine)palladium(II)

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