Circularly polarized-thermally activated delayed fluorescent materials based on chiral bicarbazole donors

Laurélie Poulard; Sitthichok Kasemthaveechok; Max Coehlo; Ramar Arun Kumar; Lucas Frédéric; Patthira Sumsalee; Timothée d’Anfray; Sen Wu; Jingxiang Wang; Tomas Matulaitis; Jeanne Crassous; Eli Zysman-Colman; Ludovic Favereau; Grégory Pieters

doi:10.1039/D2CC00998F

Circularly polarized-thermally activated delayed fluorescent materials based on chiral bicarbazole donors

Laurélie Poulard, Sitthichok Kasemthaveechok, Max Coehlo, Ramar Arun Kumar, Lucas Frédéric, Patthira Sumsalee, Timothée d’Anfray, Sen Wu, Jingxiang Wang, Tomas Matulaitis, Jeanne Crassous, Eli Zysman-Colman, Ludovic Favereau^*, Grégory Pieters^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

We describe herein a molecular design to generate circularly polarized thermally activated delayed fluorescence emitters in which chiral bicarbazole donors are connected to acceptor units via a rigid 8-membered cycle and how the nature of the donor and acceptor units affect the photophysical and chiroptical properties.

Original language	English
Number of pages	4
Journal	Chemical Communications
Volume	Advance Article
Early online date	5 May 2022
DOIs	https://doi.org/10.1039/D2CC00998F
Publication status	E-pub ahead of print - 5 May 2022

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Eli Zysman-colman SRF: New Frontiers in Multi-Resonance Thermally Activated Delayed Fluorescence Emitter Design for Organic Light-Emitting Diodes
Zysman-Colman, E. (PI)
The Royal Society
18/01/21 → 18/03/22
Project: Fellowship
Chemistry EPSRC-JSPS: EPSRC-JSPS Core-to-Core Grant Application
Zysman-Colman, E. (PI)
1/08/18 → 31/01/24
Project: Standard

Circularly polarized-thermally activated delayed fluorescent materials based on chiral bicarbazole donors (dataset)
Poulard, L. (Creator), Kasemthaveechok, S. (Creator), Coehlo, M. (Creator), Kumar, R. A. (Creator), Frédéric, L. (Creator), Sumsalee, P. (Creator), d’Anfray, T. (Creator), Wu, S. (Creator), Wang, J. (Creator), Matulaitis, T. (Creator), Crassous, J. (Creator), Zysman-Colman, E. (Creator), Favereau, L. (Creator) & Pieters, G. (Creator), University of St Andrews, 6 Jun 2022
DOI: 10.17630/16db897f-026e-4ae1-ab0c-5ef416aa8ed8
Dataset

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Poulard, L., Kasemthaveechok, S., Coehlo, M., Kumar, R. A., Frédéric, L., Sumsalee, P., d’Anfray, T., Wu, S., Wang, J., Matulaitis, T., Crassous, J., Zysman-Colman, E., Favereau, L., & Pieters, G. (2022). Circularly polarized-thermally activated delayed fluorescent materials based on chiral bicarbazole donors. Chemical Communications, Advance Article. Advance online publication. https://doi.org/10.1039/D2CC00998F

@article{5a08187ae5904f23857227be0520ad7b,

title = "Circularly polarized-thermally activated delayed fluorescent materials based on chiral bicarbazole donors",

abstract = "We describe herein a molecular design to generate circularly polarized thermally activated delayed fluorescence emitters in which chiral bicarbazole donors are connected to acceptor units via a rigid 8-membered cycle and how the nature of the donor and acceptor units affect the photophysical and chiroptical properties.",

author = "Laur{\'e}lie Poulard and Sitthichok Kasemthaveechok and Max Coehlo and Kumar, {Ramar Arun} and Lucas Fr{\'e}d{\'e}ric and Patthira Sumsalee and Timoth{\'e}e d{\textquoteright}Anfray and Sen Wu and Jingxiang Wang and Tomas Matulaitis and Jeanne Crassous and Eli Zysman-Colman and Ludovic Favereau and Gr{\'e}gory Pieters",

note = "G. P. thanks the SCBM, the “PTC du CEA” (POLEM) and the ANR (iChiralight, ANR-19-CE07-0040) for funding and David Buisson, Am{\'e}lie Goudet and Sabrina Lebrequier. J. C. and L. Fa. acknowledge the Minist{\`e}re de l{\textquoteright}Education Nationale, de la Recherche et de la Technologie, the CNRS and the Spectroscopies-CDTP core facility is also acknowledged. The St. Andrews team thanks the China Scholarship Council, 201906250199 to W. S. and 202006250026 to J. W., E. Z.-C. is a Royal Society Leverhulme Trust Senior Research fellow (SRF\R1\201089). We thank the EPSRC (EP/R035164/1) for funding.",

year = "2022",

month = may,

day = "5",

doi = "10.1039/D2CC00998F",

language = "English",

volume = "Advance Article",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

}

Poulard, L, Kasemthaveechok, S, Coehlo, M, Kumar, RA, Frédéric, L, Sumsalee, P, d’Anfray, T, Wu, S, Wang, J, Matulaitis, T, Crassous, J, Zysman-Colman, E, Favereau, L & Pieters, G 2022, 'Circularly polarized-thermally activated delayed fluorescent materials based on chiral bicarbazole donors', Chemical Communications, vol. Advance Article. https://doi.org/10.1039/D2CC00998F

TY - JOUR

T1 - Circularly polarized-thermally activated delayed fluorescent materials based on chiral bicarbazole donors

AU - Poulard, Laurélie

AU - Kasemthaveechok, Sitthichok

AU - Coehlo, Max

AU - Kumar, Ramar Arun

AU - Frédéric, Lucas

AU - Sumsalee, Patthira

AU - d’Anfray, Timothée

AU - Wu, Sen

AU - Wang, Jingxiang

AU - Matulaitis, Tomas

AU - Crassous, Jeanne

AU - Zysman-Colman, Eli

AU - Favereau, Ludovic

AU - Pieters, Grégory

N1 - G. P. thanks the SCBM, the “PTC du CEA” (POLEM) and the ANR (iChiralight, ANR-19-CE07-0040) for funding and David Buisson, Amélie Goudet and Sabrina Lebrequier. J. C. and L. Fa. acknowledge the Ministère de l’Education Nationale, de la Recherche et de la Technologie, the CNRS and the Spectroscopies-CDTP core facility is also acknowledged. The St. Andrews team thanks the China Scholarship Council, 201906250199 to W. S. and 202006250026 to J. W., E. Z.-C. is a Royal Society Leverhulme Trust Senior Research fellow (SRF\R1\201089). We thank the EPSRC (EP/R035164/1) for funding.

PY - 2022/5/5

Y1 - 2022/5/5

N2 - We describe herein a molecular design to generate circularly polarized thermally activated delayed fluorescence emitters in which chiral bicarbazole donors are connected to acceptor units via a rigid 8-membered cycle and how the nature of the donor and acceptor units affect the photophysical and chiroptical properties.

AB - We describe herein a molecular design to generate circularly polarized thermally activated delayed fluorescence emitters in which chiral bicarbazole donors are connected to acceptor units via a rigid 8-membered cycle and how the nature of the donor and acceptor units affect the photophysical and chiroptical properties.

U2 - 10.1039/D2CC00998F

DO - 10.1039/D2CC00998F

M3 - Article

SN - 1359-7345

VL - Advance Article

JO - Chemical Communications

JF - Chemical Communications

ER -

Circularly polarized-thermally activated delayed fluorescent materials based on chiral bicarbazole donors

Abstract

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Projects

Eli Zysman-colman SRF: New Frontiers in Multi-Resonance Thermally Activated Delayed Fluorescence Emitter Design for Organic Light-Emitting Diodes

Chemistry EPSRC-JSPS: EPSRC-JSPS Core-to-Core Grant Application

Datasets

Circularly polarized-thermally activated delayed fluorescent materials based on chiral bicarbazole donors (dataset)

Cite this