Chlorides, Oxochlorides, and Oxoacids of 1,8-Diphosphanaphthalene: A System with Imposed Close P...P Interaction

Petr Kilian; HL Milton; Alexandra Martha Zoya Slawin; John Derek Woollins

doi:10.1021/ic035364h

Chlorides, Oxochlorides, and Oxoacids of 1,8-Diphosphanaphthalene: A System with Imposed Close P...P Interaction

Petr Kilian, HL Milton, Alexandra Martha Zoya Slawin, John Derek Woollins

Research output: Contribution to journal › Article › peer-review

Abstract

Several new 1,8-diphosphanaphthalene oxochloro compounds and oxoacids were prepared and fully characterized. The new compounds are discussed in the broader context with other known congeners to demonstrate the variability of the diphosphanaphthalene scaffolding's bonding patterns. Three principal modes of interaction of the phosphorus moieties were observed in the series: bonding, bridging, and repulsive, resulting respectively in none, moderate, and substantial crowding and distortions. The unexpected dimeric diphosphaacenaphthene anion has been obtained from disproportionative hydrolysis of Nap(PCl2)(2) (Nap = naphthalene- 1,8-diyl).

Original language	English
Pages (from-to)	2252-2260
Number of pages	9
Journal	Inorganic Chemistry
Volume	43
Issue number	7
DOIs	https://doi.org/10.1021/ic035364h
Publication status	Published - 5 Apr 2004

Keywords

REACTION-PRODUCTS
DERIVATIVES
NAPHTHALENE
PHOSPHORUS

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10.1021/ic035364h

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abstract = "Several new 1,8-diphosphanaphthalene oxochloro compounds and oxoacids were prepared and fully characterized. The new compounds are discussed in the broader context with other known congeners to demonstrate the variability of the diphosphanaphthalene scaffolding's bonding patterns. Three principal modes of interaction of the phosphorus moieties were observed in the series: bonding, bridging, and repulsive, resulting respectively in none, moderate, and substantial crowding and distortions. The unexpected dimeric diphosphaacenaphthene anion has been obtained from disproportionative hydrolysis of Nap(PCl2)(2) (Nap = naphthalene- 1,8-diyl).",

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T1 - Chlorides, Oxochlorides, and Oxoacids of 1,8-Diphosphanaphthalene: A System with Imposed Close P...P Interaction

AU - Kilian, Petr

AU - Milton, HL

AU - Slawin, Alexandra Martha Zoya

AU - Woollins, John Derek

PY - 2004/4/5

Y1 - 2004/4/5

N2 - Several new 1,8-diphosphanaphthalene oxochloro compounds and oxoacids were prepared and fully characterized. The new compounds are discussed in the broader context with other known congeners to demonstrate the variability of the diphosphanaphthalene scaffolding's bonding patterns. Three principal modes of interaction of the phosphorus moieties were observed in the series: bonding, bridging, and repulsive, resulting respectively in none, moderate, and substantial crowding and distortions. The unexpected dimeric diphosphaacenaphthene anion has been obtained from disproportionative hydrolysis of Nap(PCl2)(2) (Nap = naphthalene- 1,8-diyl).

AB - Several new 1,8-diphosphanaphthalene oxochloro compounds and oxoacids were prepared and fully characterized. The new compounds are discussed in the broader context with other known congeners to demonstrate the variability of the diphosphanaphthalene scaffolding's bonding patterns. Three principal modes of interaction of the phosphorus moieties were observed in the series: bonding, bridging, and repulsive, resulting respectively in none, moderate, and substantial crowding and distortions. The unexpected dimeric diphosphaacenaphthene anion has been obtained from disproportionative hydrolysis of Nap(PCl2)(2) (Nap = naphthalene- 1,8-diyl).

KW - REACTION-PRODUCTS

KW - DERIVATIVES

KW - NAPHTHALENE

KW - PHOSPHORUS

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JO - Inorganic Chemistry

JF - Inorganic Chemistry

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Chlorides, Oxochlorides, and Oxoacids of 1,8-Diphosphanaphthalene: A System with Imposed Close P...P Interaction

Abstract

Keywords

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