Chloranilate Bridged Sodium Chains

C Papadimitriou; P Veltsistas; J Marek; J Novosad; Alexandra Martha Zoya Slawin; John Derek Woollins

Chloranilate Bridged Sodium Chains

C Papadimitriou, P Veltsistas, J Marek, J Novosad, Alexandra Martha Zoya Slawin, John Derek Woollins

Research output: Other contribution

Abstract

Slow crystallisation (in water glass) has been used to obtain Na-2(ca). 3H(2)O (1) and Na-2(ca)phen . 2H(2)O (2) which have been characterised by X-ray crystallography. 1:C12H12O4Na4O14, triclinic a = 6.567(1), b = 8.472(1), c = 9.816(1) Angstrom, alpha = 106.71(1), beta = 92.04(1), gamma = 92.48( 1)degrees, U = 522 Angstrom(3), P-1, Z = 1, F(000) = 308, mu(Mo-K alpha) = 0.72 mm(-1), 1700 observed [F > 4.0 sigma(F)] gave a final R = 3.56%. 2: monoclinic, a = 10.754(1), b = 19.778(2), c = 13.681(1) Angstrom, beta = 98.55(1)degrees, U = 2877 Angstrom(3), P2(1)/c, Z = 4, F(000) = 1328, mu(Mo-K alpha) = 0.31 mm(-1), 2337 observed [F > 4.0 sigma(F)] gave a final R = 5.73%. In both structures the chloranilate anions make use of chlorine atoms to complete the six coordination of the sodium centres in the layer/chain systems. (C) 1998 Published by Elsevier Science S.A. All rights reserved.

Original language	English
Volume	1
Publication status	Published - Nov 1998

Keywords

chloranilate anions
layer/chain systems
crystal structures
sodium complexes
COMPLEXES
RUTHENIUM
CRYSTAL

Cite this

@misc{162e718a4f9c4132a2fdc34dc7505ee5,

title = "Chloranilate Bridged Sodium Chains",

abstract = "Slow crystallisation (in water glass) has been used to obtain Na-2(ca). 3H(2)O (1) and Na-2(ca)phen . 2H(2)O (2) which have been characterised by X-ray crystallography. 1:C12H12O4Na4O14, triclinic a = 6.567(1), b = 8.472(1), c = 9.816(1) Angstrom, alpha = 106.71(1), beta = 92.04(1), gamma = 92.48( 1)degrees, U = 522 Angstrom(3), P-1, Z = 1, F(000) = 308, mu(Mo-K alpha) = 0.72 mm(-1), 1700 observed [F > 4.0 sigma(F)] gave a final R = 3.56%. 2: monoclinic, a = 10.754(1), b = 19.778(2), c = 13.681(1) Angstrom, beta = 98.55(1)degrees, U = 2877 Angstrom(3), P2(1)/c, Z = 4, F(000) = 1328, mu(Mo-K alpha) = 0.31 mm(-1), 2337 observed [F > 4.0 sigma(F)] gave a final R = 5.73%. In both structures the chloranilate anions make use of chlorine atoms to complete the six coordination of the sodium centres in the layer/chain systems. (C) 1998 Published by Elsevier Science S.A. All rights reserved.",

keywords = "chloranilate anions, layer/chain systems, crystal structures, sodium complexes, COMPLEXES, RUTHENIUM, CRYSTAL",

author = "C Papadimitriou and P Veltsistas and J Marek and J Novosad and Slawin, {Alexandra Martha Zoya} and Woollins, {John Derek}",

note = "Inorg Chem Comm",

year = "1998",

month = nov,

language = "English",

volume = "1",

type = "Other",

}

TY - GEN

T1 - Chloranilate Bridged Sodium Chains

AU - Papadimitriou, C

AU - Veltsistas, P

AU - Marek, J

AU - Novosad, J

AU - Slawin, Alexandra Martha Zoya

AU - Woollins, John Derek

N1 - Inorg Chem Comm

PY - 1998/11

Y1 - 1998/11

N2 - Slow crystallisation (in water glass) has been used to obtain Na-2(ca). 3H(2)O (1) and Na-2(ca)phen . 2H(2)O (2) which have been characterised by X-ray crystallography. 1:C12H12O4Na4O14, triclinic a = 6.567(1), b = 8.472(1), c = 9.816(1) Angstrom, alpha = 106.71(1), beta = 92.04(1), gamma = 92.48( 1)degrees, U = 522 Angstrom(3), P-1, Z = 1, F(000) = 308, mu(Mo-K alpha) = 0.72 mm(-1), 1700 observed [F > 4.0 sigma(F)] gave a final R = 3.56%. 2: monoclinic, a = 10.754(1), b = 19.778(2), c = 13.681(1) Angstrom, beta = 98.55(1)degrees, U = 2877 Angstrom(3), P2(1)/c, Z = 4, F(000) = 1328, mu(Mo-K alpha) = 0.31 mm(-1), 2337 observed [F > 4.0 sigma(F)] gave a final R = 5.73%. In both structures the chloranilate anions make use of chlorine atoms to complete the six coordination of the sodium centres in the layer/chain systems. (C) 1998 Published by Elsevier Science S.A. All rights reserved.

AB - Slow crystallisation (in water glass) has been used to obtain Na-2(ca). 3H(2)O (1) and Na-2(ca)phen . 2H(2)O (2) which have been characterised by X-ray crystallography. 1:C12H12O4Na4O14, triclinic a = 6.567(1), b = 8.472(1), c = 9.816(1) Angstrom, alpha = 106.71(1), beta = 92.04(1), gamma = 92.48( 1)degrees, U = 522 Angstrom(3), P-1, Z = 1, F(000) = 308, mu(Mo-K alpha) = 0.72 mm(-1), 1700 observed [F > 4.0 sigma(F)] gave a final R = 3.56%. 2: monoclinic, a = 10.754(1), b = 19.778(2), c = 13.681(1) Angstrom, beta = 98.55(1)degrees, U = 2877 Angstrom(3), P2(1)/c, Z = 4, F(000) = 1328, mu(Mo-K alpha) = 0.31 mm(-1), 2337 observed [F > 4.0 sigma(F)] gave a final R = 5.73%. In both structures the chloranilate anions make use of chlorine atoms to complete the six coordination of the sodium centres in the layer/chain systems. (C) 1998 Published by Elsevier Science S.A. All rights reserved.

KW - chloranilate anions

KW - layer/chain systems

KW - crystal structures

KW - sodium complexes

KW - COMPLEXES

KW - RUTHENIUM

KW - CRYSTAL

UR - http://www.scopus.com/inward/record.url?scp=0000910874&partnerID=8YFLogxK

M3 - Other contribution

VL - 1

ER -

Chloranilate Bridged Sodium Chains

Abstract

Keywords

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