Chiral Induction in the Ionothermal Synthesis of a 3-D Coordination Polymer

Z Lin; Alexandra Martha Zoya Slawin; Russell Edward Morris

doi:10.1021/ja070671y

Chiral Induction in the Ionothermal Synthesis of a 3-D Coordination Polymer

Z Lin, Alexandra Martha Zoya Slawin, Russell Edward Morris

Research output: Contribution to journal › Article › peer-review

Abstract

A new chiral coordination polymer, (BMIm)(2)[Ni(TMA-H)(2)(H2O)(2)], was prepared ionothermally from chiral ionic liquid. The use of L-aspartate as one component of the ionic liquid induces chirality in the resulting solid, despite the fact that the anion is not occluded by the material and that the solid itself is built from only nonchiral building blocks. Without the chiral component, an achiral compound is formed under the same synthesis conditions.

Original language	English
Pages (from-to)	4880-4881
Number of pages	3
Journal	Journal of the American Chemical Society
Volume	129
Issue number	16
DOIs	https://doi.org/10.1021/ja070671y
Publication status	Published - 25 Apr 2007

Keywords

METAL-ORGANIC FRAMEWORKS
IONIC LIQUIDS
SURFACE-AREA
HYDROGEN
CATALYSIS
MIXTURES
TEMPLATE
CRYSTALS
SOLVENTS
STORAGE

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10.1021/ja070671y

Cite this

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title = "Chiral Induction in the Ionothermal Synthesis of a 3-D Coordination Polymer",

abstract = "A new chiral coordination polymer, (BMIm)(2)[Ni(TMA-H)(2)(H2O)(2)], was prepared ionothermally from chiral ionic liquid. The use of L-aspartate as one component of the ionic liquid induces chirality in the resulting solid, despite the fact that the anion is not occluded by the material and that the solid itself is built from only nonchiral building blocks. Without the chiral component, an achiral compound is formed under the same synthesis conditions.",

keywords = "METAL-ORGANIC FRAMEWORKS, IONIC LIQUIDS, SURFACE-AREA, HYDROGEN, CATALYSIS, MIXTURES, TEMPLATE, CRYSTALS, SOLVENTS, STORAGE",

author = "Z Lin and Slawin, {Alexandra Martha Zoya} and Morris, {Russell Edward}",

year = "2007",

month = apr,

day = "25",

doi = "10.1021/ja070671y",

language = "English",

volume = "129",

pages = "4880--4881",

journal = "Journal of the American Chemical Society",

issn = "0002-7863",

publisher = "American Chemical Society (ACS)",

number = "16",

}

TY - JOUR

T1 - Chiral Induction in the Ionothermal Synthesis of a 3-D Coordination Polymer

AU - Lin, Z

AU - Slawin, Alexandra Martha Zoya

AU - Morris, Russell Edward

PY - 2007/4/25

Y1 - 2007/4/25

N2 - A new chiral coordination polymer, (BMIm)(2)[Ni(TMA-H)(2)(H2O)(2)], was prepared ionothermally from chiral ionic liquid. The use of L-aspartate as one component of the ionic liquid induces chirality in the resulting solid, despite the fact that the anion is not occluded by the material and that the solid itself is built from only nonchiral building blocks. Without the chiral component, an achiral compound is formed under the same synthesis conditions.

AB - A new chiral coordination polymer, (BMIm)(2)[Ni(TMA-H)(2)(H2O)(2)], was prepared ionothermally from chiral ionic liquid. The use of L-aspartate as one component of the ionic liquid induces chirality in the resulting solid, despite the fact that the anion is not occluded by the material and that the solid itself is built from only nonchiral building blocks. Without the chiral component, an achiral compound is formed under the same synthesis conditions.

KW - METAL-ORGANIC FRAMEWORKS

KW - IONIC LIQUIDS

KW - SURFACE-AREA

KW - HYDROGEN

KW - CATALYSIS

KW - MIXTURES

KW - TEMPLATE

KW - CRYSTALS

KW - SOLVENTS

KW - STORAGE

UR - http://www.scopus.com/inward/record.url?scp=34247543864&partnerID=8YFLogxK

U2 - 10.1021/ja070671y

DO - 10.1021/ja070671y

M3 - Article

SN - 0002-7863

VL - 129

SP - 4880

EP - 4881

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 16

ER -

Chiral Induction in the Ionothermal Synthesis of a 3-D Coordination Polymer

Abstract

Keywords

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EP/C006526/1: The ionothermal synthesis of zeolites and zeolites analogues

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Chiral Induction in the Ionothermal Synthesis of a 3-D Coordination Polymer

Abstract

Keywords

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Projects

EP/C006526/1: The ionothermal synthesis of zeolites and zeolites analogues

Cite this