Chemoselective Oxidation of Secondary Alcohols Using a Ruthenium Phenylindenyl Complex

Simone Manzini; César Alejandro Urbina Blanco; Steven Patrick Nolan

doi:10.1021/om301156v

Chemoselective Oxidation of Secondary Alcohols Using a Ruthenium Phenylindenyl Complex

Simone Manzini, César Alejandro Urbina Blanco, Steven Patrick Nolan

Research output: Contribution to journal › Article › peer-review

Abstract

A straightforward catalytic alcohol oxidation procedure using the recently reported complex [RuCl(PPh3)2(3-phenylindenyl)] (1) with KHMDS as cocatalyst, in acetone as the oxidant, is reported. Complex 1 shows remarkable chemoselectivity in oxidizing secondary alcohols to ketones.

Original language	English
Pages (from-to)	660-664
Number of pages	5
Journal	Organometallics
Volume	32
Issue number	2
Early online date	15 Jan 2013
DOIs	https://doi.org/10.1021/om301156v
Publication status	Published - 28 Jan 2013

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@article{00158669a12046f392a33610634d0ebd,

title = "Chemoselective Oxidation of Secondary Alcohols Using a Ruthenium Phenylindenyl Complex",

abstract = "A straightforward catalytic alcohol oxidation procedure using the recently reported complex [RuCl(PPh3)2(3-phenylindenyl)] (1) with KHMDS as cocatalyst, in acetone as the oxidant, is reported. Complex 1 shows remarkable chemoselectivity in oxidizing secondary alcohols to ketones.",

author = "Simone Manzini and \{Urbina Blanco\}, \{C{\'e}sar Alejandro\} and Nolan, \{Steven Patrick\}",

year = "2013",

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doi = "10.1021/om301156v",

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T1 - Chemoselective Oxidation of Secondary Alcohols Using a Ruthenium Phenylindenyl Complex

AU - Manzini, Simone

AU - Urbina Blanco, César Alejandro

AU - Nolan, Steven Patrick

PY - 2013/1/28

Y1 - 2013/1/28

N2 - A straightforward catalytic alcohol oxidation procedure using the recently reported complex [RuCl(PPh3)2(3-phenylindenyl)] (1) with KHMDS as cocatalyst, in acetone as the oxidant, is reported. Complex 1 shows remarkable chemoselectivity in oxidizing secondary alcohols to ketones.

AB - A straightforward catalytic alcohol oxidation procedure using the recently reported complex [RuCl(PPh3)2(3-phenylindenyl)] (1) with KHMDS as cocatalyst, in acetone as the oxidant, is reported. Complex 1 shows remarkable chemoselectivity in oxidizing secondary alcohols to ketones.

UR - https://www.scopus.com/pages/publications/84872969515

U2 - 10.1021/om301156v

DO - 10.1021/om301156v

M3 - Article

SN - 0276-7333

VL - 32

SP - 660

EP - 664

JO - Organometallics

JF - Organometallics

IS - 2

ER -

Chemoselective Oxidation of Secondary Alcohols Using a Ruthenium Phenylindenyl Complex

Abstract

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