Chemoselective Oxidation of Secondary Alcohols Using a Ruthenium Phenylindenyl Complex

Simone Manzini; César Alejandro Urbina Blanco; Steven Patrick Nolan

doi:10.1021/om301156v

Chemoselective Oxidation of Secondary Alcohols Using a Ruthenium Phenylindenyl Complex

Simone Manzini, César Alejandro Urbina Blanco, Steven Patrick Nolan

Research output: Contribution to journal › Article › peer-review

38 Citations (Scopus)

Abstract

A straightforward catalytic alcohol oxidation procedure using the recently reported complex [RuCl(PPh3)2(3-phenylindenyl)] (1) with KHMDS as cocatalyst, in acetone as the oxidant, is reported. Complex 1 shows remarkable chemoselectivity in oxidizing secondary alcohols to ketones.

Original language	English
Pages (from-to)	660-664
Number of pages	5
Journal	Organometallics
Volume	32
Issue number	2
Early online date	15 Jan 2013
DOIs	https://doi.org/10.1021/om301156v
Publication status	Published - 28 Jan 2013

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title = "Chemoselective Oxidation of Secondary Alcohols Using a Ruthenium Phenylindenyl Complex",

abstract = "A straightforward catalytic alcohol oxidation procedure using the recently reported complex [RuCl(PPh3)2(3-phenylindenyl)] (1) with KHMDS as cocatalyst, in acetone as the oxidant, is reported. Complex 1 shows remarkable chemoselectivity in oxidizing secondary alcohols to ketones.",

author = "Simone Manzini and {Urbina Blanco}, {C{\'e}sar Alejandro} and Nolan, {Steven Patrick}",

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AU - Manzini, Simone

AU - Urbina Blanco, César Alejandro

AU - Nolan, Steven Patrick

PY - 2013/1/28

Y1 - 2013/1/28

N2 - A straightforward catalytic alcohol oxidation procedure using the recently reported complex [RuCl(PPh3)2(3-phenylindenyl)] (1) with KHMDS as cocatalyst, in acetone as the oxidant, is reported. Complex 1 shows remarkable chemoselectivity in oxidizing secondary alcohols to ketones.

AB - A straightforward catalytic alcohol oxidation procedure using the recently reported complex [RuCl(PPh3)2(3-phenylindenyl)] (1) with KHMDS as cocatalyst, in acetone as the oxidant, is reported. Complex 1 shows remarkable chemoselectivity in oxidizing secondary alcohols to ketones.

U2 - 10.1021/om301156v

DO - 10.1021/om301156v

M3 - Article

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SP - 660

EP - 664

JO - Organometallics

JF - Organometallics

IS - 2

ER -

Chemoselective Oxidation of Secondary Alcohols Using a Ruthenium Phenylindenyl Complex

Abstract

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