Characterization of equatorial and axial six-membered-ring peroxyl radicals

Gino A. DiLabio; Keith U. Ingold; John C. Walton

doi:10.1021/jo7014592

Characterization of equatorial and axial six-membered-ring peroxyl radicals

Gino A. DiLabio, Keith U. Ingold, John C. Walton

Research output: Contribution to journal › Article › peer-review

Abstract

Spectroscopic data are consistent with computations that show that, in their most stable conformations, the peroxyl moiety is equatorial in cyclohexylperoxyl radicals and axial in oxa- and most polyoxacyclohexyl-2-peroxyl radicals.

Original language	English
Pages (from-to)	8095-8098
Number of pages	4
Journal	The Journal of Organic Chemistry
Volume	72
Issue number	21
DOIs	https://doi.org/10.1021/jo7014592
Publication status	Published - 12 Oct 2007

Keywords

CYCLOALKYLMETHYL RADICALS
CYCLOHEXYLMETHYL
CYCLOHEXANE
DENSITY

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10.1021/jo7014592

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@article{95f7a70a2a8442b0b775b8748eb370ad,

title = "Characterization of equatorial and axial six-membered-ring peroxyl radicals",

abstract = "Spectroscopic data are consistent with computations that show that, in their most stable conformations, the peroxyl moiety is equatorial in cyclohexylperoxyl radicals and axial in oxa- and most polyoxacyclohexyl-2-peroxyl radicals.",

keywords = "CYCLOALKYLMETHYL RADICALS, CYCLOHEXYLMETHYL, CYCLOHEXANE, DENSITY",

author = "DiLabio, {Gino A.} and Ingold, {Keith U.} and Walton, {John C.}",

year = "2007",

month = oct,

day = "12",

doi = "10.1021/jo7014592",

language = "English",

volume = "72",

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journal = "The Journal of Organic Chemistry",

issn = "0022-3263",

publisher = "American Chemical Society (ACS)",

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TY - JOUR

T1 - Characterization of equatorial and axial six-membered-ring peroxyl radicals

AU - DiLabio, Gino A.

AU - Ingold, Keith U.

AU - Walton, John C.

PY - 2007/10/12

Y1 - 2007/10/12

N2 - Spectroscopic data are consistent with computations that show that, in their most stable conformations, the peroxyl moiety is equatorial in cyclohexylperoxyl radicals and axial in oxa- and most polyoxacyclohexyl-2-peroxyl radicals.

AB - Spectroscopic data are consistent with computations that show that, in their most stable conformations, the peroxyl moiety is equatorial in cyclohexylperoxyl radicals and axial in oxa- and most polyoxacyclohexyl-2-peroxyl radicals.

KW - CYCLOALKYLMETHYL RADICALS

KW - CYCLOHEXYLMETHYL

KW - CYCLOHEXANE

KW - DENSITY

UR - http://www.scopus.com/inward/record.url?scp=35348820516&partnerID=8YFLogxK

U2 - 10.1021/jo7014592

DO - 10.1021/jo7014592

M3 - Article

SN - 0022-3263

VL - 72

SP - 8095

EP - 8098

JO - The Journal of Organic Chemistry

JF - The Journal of Organic Chemistry

IS - 21

ER -

Characterization of equatorial and axial six-membered-ring peroxyl radicals

Abstract

Keywords

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