Chains of fused rings in the hydrogen-bonded structure of meso-6,13-diamino-6,13-dimethyl-1,4,8,11-tetraazacyclotetradecane-2,2 '-biphenol (1/2)

A J  Lough; R M  Gregson; G  Ferguson; C  Glidewell

Chains of fused rings in the hydrogen-bonded structure of meso-6,13-diamino-6,13-dimethyl-1,4,8,11-tetraazacyclotetradecane-2,2 '-biphenol (1/2)

A J Lough, R M Gregson, G Ferguson, C Glidewell

School of Chemistry

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

The title compound is a salt, [C12H32N6](2+). 2[HOC6H4C6H4O](-). The centrosymmetric cation contains two intramolecular ND H ... N hydrogen bonds with an N ... N distance of 2.8290 (13) Angstrom, and the pendent amino groups are in axial sites; the anion contains an intramolecular O-H ... O hydrogen bond with an O ... O distance of 2.4656 (11) Angstrom. The ions are linked into continuous chains by means of four types of N-H ... O hydrogen bonds with N ... O distances ranging from 2.7238 (12) Angstrom to 3.3091 (13) Angstrom, associated with N-H ... O angles in the range 148-160 degrees.

Original language	English
Pages (from-to)	859-861
Number of pages	3
Journal	Acta Crystallographica Section C-Crystal Structure Communications
Volume	56
Publication status	Published - Jul 2000

Keywords

CYCLAM

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title = "Chains of fused rings in the hydrogen-bonded structure of meso-6,13-diamino-6,13-dimethyl-1,4,8,11-tetraazacyclotetradecane-2,2 '-biphenol (1/2)",

abstract = "The title compound is a salt, [C12H32N6](2+). 2[HOC6H4C6H4O](-). The centrosymmetric cation contains two intramolecular ND H ... N hydrogen bonds with an N ... N distance of 2.8290 (13) Angstrom, and the pendent amino groups are in axial sites; the anion contains an intramolecular O-H ... O hydrogen bond with an O ... O distance of 2.4656 (11) Angstrom. The ions are linked into continuous chains by means of four types of N-H ... O hydrogen bonds with N ... O distances ranging from 2.7238 (12) Angstrom to 3.3091 (13) Angstrom, associated with N-H ... O angles in the range 148-160 degrees.",

keywords = "CYCLAM",

author = "Lough, {A J} and Gregson, {R M} and G Ferguson and C Glidewell",

year = "2000",

month = jul,

language = "English",

volume = "56",

pages = "859--861",

journal = "Acta Crystallographica Section C-Crystal Structure Communications",

issn = "1600-5759",

publisher = "International Union of Crystallography",

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TY - JOUR

T1 - Chains of fused rings in the hydrogen-bonded structure of meso-6,13-diamino-6,13-dimethyl-1,4,8,11-tetraazacyclotetradecane-2,2 '-biphenol (1/2)

AU - Lough, A J

AU - Gregson, R M

AU - Ferguson, G

AU - Glidewell, C

PY - 2000/7

Y1 - 2000/7

N2 - The title compound is a salt, [C12H32N6](2+). 2[HOC6H4C6H4O](-). The centrosymmetric cation contains two intramolecular ND H ... N hydrogen bonds with an N ... N distance of 2.8290 (13) Angstrom, and the pendent amino groups are in axial sites; the anion contains an intramolecular O-H ... O hydrogen bond with an O ... O distance of 2.4656 (11) Angstrom. The ions are linked into continuous chains by means of four types of N-H ... O hydrogen bonds with N ... O distances ranging from 2.7238 (12) Angstrom to 3.3091 (13) Angstrom, associated with N-H ... O angles in the range 148-160 degrees.

AB - The title compound is a salt, [C12H32N6](2+). 2[HOC6H4C6H4O](-). The centrosymmetric cation contains two intramolecular ND H ... N hydrogen bonds with an N ... N distance of 2.8290 (13) Angstrom, and the pendent amino groups are in axial sites; the anion contains an intramolecular O-H ... O hydrogen bond with an O ... O distance of 2.4656 (11) Angstrom. The ions are linked into continuous chains by means of four types of N-H ... O hydrogen bonds with N ... O distances ranging from 2.7238 (12) Angstrom to 3.3091 (13) Angstrom, associated with N-H ... O angles in the range 148-160 degrees.

KW - CYCLAM

M3 - Article

SN - 1600-5759

VL - 56

SP - 859

EP - 861

JO - Acta Crystallographica Section C-Crystal Structure Communications

JF - Acta Crystallographica Section C-Crystal Structure Communications

ER -

Chains of fused rings in the hydrogen-bonded structure of meso-6,13-diamino-6,13-dimethyl-1,4,8,11-tetraazacyclotetradecane-2,2 '-biphenol (1/2)

Abstract

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