Centrosymmetric molecular strings in the hydrogen-bonded structure of 4,4 '-bipyridyl-4,4 '-thiodiphenol (3/2)

A J  Lough; R M  Gregson; G  Ferguson; C  Glidewell

Centrosymmetric molecular strings in the hydrogen-bonded structure of 4,4 '-bipyridyl-4,4 '-thiodiphenol (3/2)

A J Lough, R M Gregson, G Ferguson, C Glidewell

School of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The title compound, 3C(10)H(8)N(2). 2C(12)H(10)O(2)S. contains five-component molecular strings lying across centres of inversion and containing alternating 4,4'-bipyridyl and 4,4'-thiodiphenol units; the molecular components are linked by just two types of O-H ... N hydrogen bonds [O ... N 2.736(2) and 2.683(2) Angstrom; O-H ... N 162 and 169 degrees]. Each string is connected to two neighbouring strings by means of aromatic pi...pi stacking interactions across centres of inversion to give continuous chains running parallel to [10 (1) over bar].

Original language	English
Pages (from-to)	1890-1892
Number of pages	3
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	55
Publication status	Published - 15 Nov 1999

Keywords

ADDUCTS
CRYSTAL
CHAINS
4,4'-ISOPROPYLIDENEDIPHENOL(1/1)
1,4-DIAZABICYCLO<2.2.2>OCTANE
4,4'-THIODIPHENOL(1/1)
4,4'-BIPYRIDYL
BISPHENOLS
PIPERAZINE
RINGS

Cite this

@article{bc5a7158ed8b4e1c9b753f0aea61ab14,

title = "Centrosymmetric molecular strings in the hydrogen-bonded structure of 4,4 '-bipyridyl-4,4 '-thiodiphenol (3/2)",

abstract = "The title compound, 3C(10)H(8)N(2). 2C(12)H(10)O(2)S. contains five-component molecular strings lying across centres of inversion and containing alternating 4,4'-bipyridyl and 4,4'-thiodiphenol units; the molecular components are linked by just two types of O-H ... N hydrogen bonds [O ... N 2.736(2) and 2.683(2) Angstrom; O-H ... N 162 and 169 degrees]. Each string is connected to two neighbouring strings by means of aromatic pi...pi stacking interactions across centres of inversion to give continuous chains running parallel to [10 (1) over bar].",

keywords = "ADDUCTS, CRYSTAL, CHAINS, 4,4'-ISOPROPYLIDENEDIPHENOL(1/1), 1,4-DIAZABICYCLO<2.2.2>OCTANE, 4,4'-THIODIPHENOL(1/1), 4,4'-BIPYRIDYL, BISPHENOLS, PIPERAZINE, RINGS",

author = "Lough, \{A J\} and Gregson, \{R M\} and G Ferguson and C Glidewell",

year = "1999",

month = nov,

day = "15",

language = "English",

volume = "55",

pages = "1890--1892",

journal = "Acta Crystallographica Section C: Crystal Structure Communications",

issn = "0108-2701",

publisher = "International Union of Crystallography",

}

TY - JOUR

T1 - Centrosymmetric molecular strings in the hydrogen-bonded structure of 4,4 '-bipyridyl-4,4 '-thiodiphenol (3/2)

AU - Lough, A J

AU - Gregson, R M

AU - Ferguson, G

AU - Glidewell, C

PY - 1999/11/15

Y1 - 1999/11/15

N2 - The title compound, 3C(10)H(8)N(2). 2C(12)H(10)O(2)S. contains five-component molecular strings lying across centres of inversion and containing alternating 4,4'-bipyridyl and 4,4'-thiodiphenol units; the molecular components are linked by just two types of O-H ... N hydrogen bonds [O ... N 2.736(2) and 2.683(2) Angstrom; O-H ... N 162 and 169 degrees]. Each string is connected to two neighbouring strings by means of aromatic pi...pi stacking interactions across centres of inversion to give continuous chains running parallel to [10 (1) over bar].

AB - The title compound, 3C(10)H(8)N(2). 2C(12)H(10)O(2)S. contains five-component molecular strings lying across centres of inversion and containing alternating 4,4'-bipyridyl and 4,4'-thiodiphenol units; the molecular components are linked by just two types of O-H ... N hydrogen bonds [O ... N 2.736(2) and 2.683(2) Angstrom; O-H ... N 162 and 169 degrees]. Each string is connected to two neighbouring strings by means of aromatic pi...pi stacking interactions across centres of inversion to give continuous chains running parallel to [10 (1) over bar].

KW - ADDUCTS

KW - CRYSTAL

KW - CHAINS

KW - 4,4'-ISOPROPYLIDENEDIPHENOL(1/1)

KW - 1,4-DIAZABICYCLO<2.2.2>OCTANE

KW - 4,4'-THIODIPHENOL(1/1)

KW - 4,4'-BIPYRIDYL

KW - BISPHENOLS

KW - PIPERAZINE

KW - RINGS

UR - https://www.scopus.com/pages/publications/0346703092

M3 - Article

SN - 0108-2701

VL - 55

SP - 1890

EP - 1892

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

ER -

Centrosymmetric molecular strings in the hydrogen-bonded structure of 4,4 '-bipyridyl-4,4 '-thiodiphenol (3/2)

Abstract

Keywords

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