Cationic copper(I) complexes as efficient precatalysts for the hydrosilylation of carbonyl compounds

S Diez-Gonzalez; NM Scott; Steven Patrick Nolan

doi:10.1021/om0600487

Cationic copper(I) complexes as efficient precatalysts for the hydrosilylation of carbonyl compounds

S Diez-Gonzalez, NM Scott, Steven Patrick Nolan

Research output: Contribution to journal › Article › peer-review

Abstract

Novel cationic copper complexes bearing two N-heterocyclic carbenes (NHCs) have been synthesized and fully characterized. These air- and moisture-stable complexes were found to be highly active toward the hydrosilylation of ketones with varying steric congestion, aldehydes (even enolizable ones), and esters.

Original language	English
Pages (from-to)	2355-2358
Number of pages	4
Journal	Organometallics
Volume	25
Issue number	9
DOIs	https://doi.org/10.1021/om0600487
Publication status	Published - 24 Apr 2006

Keywords

HETEROCYCLIC CARBENE COMPLEXES
ALPHA,BETA-UNSATURATED KETONES
CONJUGATE REDUCTION
OLEFIN METATHESIS
STABLE CARBENES
ARYL CHLORIDES
HYDRIDE
CATALYSTS
LIGANDS
<(PH3P)CUH>6

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title = "Cationic copper(I) complexes as efficient precatalysts for the hydrosilylation of carbonyl compounds",

abstract = "Novel cationic copper complexes bearing two N-heterocyclic carbenes (NHCs) have been synthesized and fully characterized. These air- and moisture-stable complexes were found to be highly active toward the hydrosilylation of ketones with varying steric congestion, aldehydes (even enolizable ones), and esters.",

keywords = "HETEROCYCLIC CARBENE COMPLEXES, ALPHA,BETA-UNSATURATED KETONES, CONJUGATE REDUCTION, OLEFIN METATHESIS, STABLE CARBENES, ARYL CHLORIDES, HYDRIDE, CATALYSTS, LIGANDS, <(PH3P)CUH>6",

author = "S Diez-Gonzalez and NM Scott and Nolan, \{Steven Patrick\}",

year = "2006",

month = apr,

day = "24",

doi = "10.1021/om0600487",

language = "English",

volume = "25",

pages = "2355--2358",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society (ACS)",

number = "9",

}

TY - JOUR

T1 - Cationic copper(I) complexes as efficient precatalysts for the hydrosilylation of carbonyl compounds

AU - Diez-Gonzalez, S

AU - Scott, NM

AU - Nolan, Steven Patrick

PY - 2006/4/24

Y1 - 2006/4/24

N2 - Novel cationic copper complexes bearing two N-heterocyclic carbenes (NHCs) have been synthesized and fully characterized. These air- and moisture-stable complexes were found to be highly active toward the hydrosilylation of ketones with varying steric congestion, aldehydes (even enolizable ones), and esters.

AB - Novel cationic copper complexes bearing two N-heterocyclic carbenes (NHCs) have been synthesized and fully characterized. These air- and moisture-stable complexes were found to be highly active toward the hydrosilylation of ketones with varying steric congestion, aldehydes (even enolizable ones), and esters.

KW - HETEROCYCLIC CARBENE COMPLEXES

KW - ALPHA,BETA-UNSATURATED KETONES

KW - CONJUGATE REDUCTION

KW - OLEFIN METATHESIS

KW - STABLE CARBENES

KW - ARYL CHLORIDES

KW - HYDRIDE

KW - CATALYSTS

KW - LIGANDS

KW - <(PH3P)CUH>6

UR - https://www.scopus.com/pages/publications/33646413657

U2 - 10.1021/om0600487

DO - 10.1021/om0600487

M3 - Article

SN - 0276-7333

VL - 25

SP - 2355

EP - 2358

JO - Organometallics

JF - Organometallics

IS - 9

ER -

Cationic copper(I) complexes as efficient precatalysts for the hydrosilylation of carbonyl compounds

Abstract

Keywords

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