catena-poly[[[{N-(6-amino-3,4-dihydro-3-methyl-5-nitroso-4-oxopyrimidin-2-yl)glycinato-O}penta-aquastrontium]-mu-N-(6-amino-3,4-dihydro-3-methyl-5-nitroso-4-oxopyrimidin-2-yl)glycinato-O : O '] monohydrate]: coordination polymer chains linked by hydrogen bonds into a three-dimensional framework

C  Glidewell; J N  Low; P A  Mascaros; R C  Martos; M D G  Valero

doi:10.1107/S0108270101017887

catena-poly[[[{N-(6-amino-3,4-dihydro-3-methyl-5-nitroso-4-oxopyrimidin-2-yl)glycinato-O}penta-aquastrontium]-mu-N-(6-amino-3,4-dihydro-3-methyl-5-nitroso-4-oxopyrimidin-2-yl)glycinato-O : O '] monohydrate]: coordination polymer chains linked by hydrogen bonds into a three-dimensional framework

C Glidewell, J N Low, P A Mascaros, R C Martos, M D G Valero

School of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

In the title compound, [Sr(C7H8N5O4)(2)(H2O)(5)].H2O, one of the anionic (C7H8N5O4)(-) ligands acts as a simple monodentate ligand coordinated via a carboxyl O atom, while the other acts as a bridging ligand between pairs of Sr atoms, utilizing one carboxyl O and the nitroso O atom, so generating a one-dimensional coordination polymer. Five water molecules are coordinated to Sr, resulting in eight-coordination in the form of a distorted square antiprism, while the sixth water molecule is hydrogen bonded to a coordinated water. The coordination polymer chains are reinforced by O-H...N and O-H...O hydrogen bonds and are linked into a three-dimensional framework by an extensive series of N-H...O and O-H...O hydrogen bonds.

Original language	English
Number of pages	4
Journal	Acta Crystallographica Section C-Crystal Structure Communications
Volume	58
DOIs	https://doi.org/10.1107/S0108270101017887
Publication status	Published - Jan 2002

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Glidewell, C., Low, J. N., Mascaros, P. A., Martos, R. C., & Valero, M. D. G. (2002). catena-poly[[[{N-(6-amino-3,4-dihydro-3-methyl-5-nitroso-4-oxopyrimidin-2-yl)glycinato-O}penta-aquastrontium]-mu-N-(6-amino-3,4-dihydro-3-methyl-5-nitroso-4-oxopyrimidin-2-yl)glycinato-O : O '] monohydrate]: coordination polymer chains linked by hydrogen bonds into a three-dimensional framework. Acta Crystallographica Section C-Crystal Structure Communications, 58. https://doi.org/10.1107/S0108270101017887

Glidewell, C ; Low, J N ; Mascaros, P A et al. / catena-poly[[[{N-(6-amino-3,4-dihydro-3-methyl-5-nitroso-4-oxopyrimidin-2-yl)glycinato-O}penta-aquastrontium]-mu-N-(6-amino-3,4-dihydro-3-methyl-5-nitroso-4-oxopyrimidin-2-yl)glycinato-O : O '] monohydrate]: coordination polymer chains linked by hydrogen bonds into a three-dimensional framework. In: Acta Crystallographica Section C-Crystal Structure Communications. 2002 ; Vol. 58.

@article{7ae7df8024bf4941a819f03738a72247,

title = "catena-poly[[[{N-(6-amino-3,4-dihydro-3-methyl-5-nitroso-4-oxopyrimidin-2-yl)glycinato-O}penta-aquastrontium]-mu-N-(6-amino-3,4-dihydro-3-methyl-5-nitroso-4-oxopyrimidin-2-yl)glycinato-O : O '] monohydrate]: coordination polymer chains linked by hydrogen bonds into a three-dimensional framework",

abstract = "In the title compound, [Sr(C7H8N5O4)(2)(H2O)(5)].H2O, one of the anionic (C7H8N5O4)(-) ligands acts as a simple monodentate ligand coordinated via a carboxyl O atom, while the other acts as a bridging ligand between pairs of Sr atoms, utilizing one carboxyl O and the nitroso O atom, so generating a one-dimensional coordination polymer. Five water molecules are coordinated to Sr, resulting in eight-coordination in the form of a distorted square antiprism, while the sixth water molecule is hydrogen bonded to a coordinated water. The coordination polymer chains are reinforced by O-H...N and O-H...O hydrogen bonds and are linked into a three-dimensional framework by an extensive series of N-H...O and O-H...O hydrogen bonds.",

author = "C Glidewell and Low, {J N} and Mascaros, {P A} and Martos, {R C} and Valero, {M D G}",

year = "2002",

month = jan,

doi = "10.1107/S0108270101017887",

language = "English",

volume = "58",

journal = "Acta Crystallographica Section C-Crystal Structure Communications",

issn = "1600-5759",

publisher = "International Union of Crystallography",

}

Glidewell, C, Low, JN, Mascaros, PA, Martos, RC & Valero, MDG 2002, 'catena-poly[[[{N-(6-amino-3,4-dihydro-3-methyl-5-nitroso-4-oxopyrimidin-2-yl)glycinato-O}penta-aquastrontium]-mu-N-(6-amino-3,4-dihydro-3-methyl-5-nitroso-4-oxopyrimidin-2-yl)glycinato-O : O '] monohydrate]: coordination polymer chains linked by hydrogen bonds into a three-dimensional framework', Acta Crystallographica Section C-Crystal Structure Communications, vol. 58. https://doi.org/10.1107/S0108270101017887

catena-poly[[[{N-(6-amino-3,4-dihydro-3-methyl-5-nitroso-4-oxopyrimidin-2-yl)glycinato-O}penta-aquastrontium]-mu-N-(6-amino-3,4-dihydro-3-methyl-5-nitroso-4-oxopyrimidin-2-yl)glycinato-O : O '] monohydrate]: coordination polymer chains linked by hydrogen bonds into a three-dimensional framework. / Glidewell, C ; Low, J N ; Mascaros, P A et al.
In: Acta Crystallographica Section C-Crystal Structure Communications, Vol. 58, 01.2002.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - catena-poly[[[{N-(6-amino-3,4-dihydro-3-methyl-5-nitroso-4-oxopyrimidin-2-yl)glycinato-O}penta-aquastrontium]-mu-N-(6-amino-3,4-dihydro-3-methyl-5-nitroso-4-oxopyrimidin-2-yl)glycinato-O : O '] monohydrate]: coordination polymer chains linked by hydrogen bonds into a three-dimensional framework

AU - Glidewell, C

AU - Low, J N

AU - Mascaros, P A

AU - Martos, R C

AU - Valero, M D G

PY - 2002/1

Y1 - 2002/1

N2 - In the title compound, [Sr(C7H8N5O4)(2)(H2O)(5)].H2O, one of the anionic (C7H8N5O4)(-) ligands acts as a simple monodentate ligand coordinated via a carboxyl O atom, while the other acts as a bridging ligand between pairs of Sr atoms, utilizing one carboxyl O and the nitroso O atom, so generating a one-dimensional coordination polymer. Five water molecules are coordinated to Sr, resulting in eight-coordination in the form of a distorted square antiprism, while the sixth water molecule is hydrogen bonded to a coordinated water. The coordination polymer chains are reinforced by O-H...N and O-H...O hydrogen bonds and are linked into a three-dimensional framework by an extensive series of N-H...O and O-H...O hydrogen bonds.

AB - In the title compound, [Sr(C7H8N5O4)(2)(H2O)(5)].H2O, one of the anionic (C7H8N5O4)(-) ligands acts as a simple monodentate ligand coordinated via a carboxyl O atom, while the other acts as a bridging ligand between pairs of Sr atoms, utilizing one carboxyl O and the nitroso O atom, so generating a one-dimensional coordination polymer. Five water molecules are coordinated to Sr, resulting in eight-coordination in the form of a distorted square antiprism, while the sixth water molecule is hydrogen bonded to a coordinated water. The coordination polymer chains are reinforced by O-H...N and O-H...O hydrogen bonds and are linked into a three-dimensional framework by an extensive series of N-H...O and O-H...O hydrogen bonds.

U2 - 10.1107/S0108270101017887

DO - 10.1107/S0108270101017887

M3 - Article

SN - 1600-5759

VL - 58

JO - Acta Crystallographica Section C-Crystal Structure Communications

JF - Acta Crystallographica Section C-Crystal Structure Communications

ER -

Glidewell C, Low JN, Mascaros PA, Martos RC, Valero MDG. catena-poly[[[{N-(6-amino-3,4-dihydro-3-methyl-5-nitroso-4-oxopyrimidin-2-yl)glycinato-O}penta-aquastrontium]-mu-N-(6-amino-3,4-dihydro-3-methyl-5-nitroso-4-oxopyrimidin-2-yl)glycinato-O : O '] monohydrate]: coordination polymer chains linked by hydrogen bonds into a three-dimensional framework. Acta Crystallographica Section C-Crystal Structure Communications. 2002 Jan;58. doi: 10.1107/S0108270101017887