Catalytic deuteration of silanes mediated by N-heterocyclic carbene-Ir(III)complexes

George Fortman; H Jacobsen; Luigi Cavallo; Steven Patrick Nolan

doi:10.1039/C1CC13492B

Catalytic deuteration of silanes mediated by N-heterocyclic carbene-Ir(III)complexes

George Fortman, H Jacobsen, Luigi Cavallo, Steven Patrick Nolan

Research output: Contribution to journal › Article › peer-review

Abstract

The catalytic activity of a series of coordinatively unsaturated
NHC-M(III) (M = Rh, Ir; NHC = N-heterocyclic carbene)
complexes was tested in the deuteration of secondary and
tertiary silanes. Among these, [IrCl(ItBu0)2] provides the highest
conversions to the deuterated species. Mechanistic studies highlight
the reversible nature of the ortho-metalation reaction.

Original language	English
Pages (from-to)	9723-9725
Number of pages	3
Journal	Chemical Communications
Volume	47
Early online date	22 Jul 2011
DOIs	https://doi.org/10.1039/C1CC13492B
Publication status	Published - 2011

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10.1039/C1CC13492B

Molecular assembly using gold catalysis: Molecular assembly using gold catalysis
Nolan, S. P. (PI)
EPSRC
1/01/10 → 31/12/12
Project: Standard

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title = "Catalytic deuteration of silanes mediated by N-heterocyclic carbene-Ir(III)complexes",

abstract = "The catalytic activity of a series of coordinatively unsaturatedNHC-M(III) (M = Rh, Ir; NHC = N-heterocyclic carbene)complexes was tested in the deuteration of secondary andtertiary silanes. Among these, [IrCl(ItBu0)2] provides the highestconversions to the deuterated species. Mechanistic studies highlightthe reversible nature of the ortho-metalation reaction.",

author = "George Fortman and H Jacobsen and Luigi Cavallo and Nolan, {Steven Patrick}",

year = "2011",

doi = "10.1039/C1CC13492B",

language = "English",

volume = "47",

pages = "9723--9725",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

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T1 - Catalytic deuteration of silanes mediated by N-heterocyclic carbene-Ir(III)complexes

AU - Fortman, George

AU - Jacobsen, H

AU - Cavallo, Luigi

AU - Nolan, Steven Patrick

PY - 2011

Y1 - 2011

N2 - The catalytic activity of a series of coordinatively unsaturatedNHC-M(III) (M = Rh, Ir; NHC = N-heterocyclic carbene)complexes was tested in the deuteration of secondary andtertiary silanes. Among these, [IrCl(ItBu0)2] provides the highestconversions to the deuterated species. Mechanistic studies highlightthe reversible nature of the ortho-metalation reaction.

AB - The catalytic activity of a series of coordinatively unsaturatedNHC-M(III) (M = Rh, Ir; NHC = N-heterocyclic carbene)complexes was tested in the deuteration of secondary andtertiary silanes. Among these, [IrCl(ItBu0)2] provides the highestconversions to the deuterated species. Mechanistic studies highlightthe reversible nature of the ortho-metalation reaction.

U2 - 10.1039/C1CC13492B

DO - 10.1039/C1CC13492B

M3 - Article

SN - 1359-7345

VL - 47

SP - 9723

EP - 9725

JO - Chemical Communications

JF - Chemical Communications

ER -

Catalytic deuteration of silanes mediated by N-heterocyclic carbene-Ir(III)complexes

Abstract

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Molecular assembly using gold catalysis: Molecular assembly using gold catalysis

Cite this