Catalytic cross-coupling reactions mediated by palladium/nucleophilic carbene systems

A C Hillier, G A Grasa, M S Viciu, H M Lee, C L Yang, Steven Patrick Nolan

Research output: Contribution to journalArticlepeer-review

491 Citations (Scopus)

Abstract

In this mini-review, we present a summary of our recent work in the field of palladium-catalyzed cross-coupling reactions, with emphasis on the use of nucleophilic N-heterocyclic carbenes (NHC) as ancillary ligand. The palladium-mediated coupling reactions investigated include the Suzuki-Miyaura, Kumada-Tamao-Corriu, Heck, Sonogashira, Stille, Hiyama and aryl animation reactions. (C) 2002 Elsevier Science B.V. All rights reserved.

Original languageEnglish
Pages (from-to)69-82
Number of pages14
JournalJournal of Organometallic Chemistry
Volume653
Issue number1-2
Publication statusPublished - 1 Jul 2002

Keywords

  • cross-coupling reactions
  • N-heterocyclic carbenes
  • palladium
  • N-HETEROCYCLIC CARBENES
  • PALLADIUM/IMIDAZOLIUM CHLORIDE SYSTEM
  • HYPERVALENT SILOXANE DERIVATIVES
  • OLEFIN METATHESIS CATALYSTS
  • ROOM-TEMPERATURE AMINATION
  • NICKEL-PHOSPHINE COMPLEXES
  • HIGHLY-ACTIVE CATALYST
  • ARYL CHLORIDES
  • HECK REACTION
  • ORGANIC HALIDES

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