Abstract
In this mini-review, we present a summary of our recent work in the field of palladium-catalyzed cross-coupling reactions, with emphasis on the use of nucleophilic N-heterocyclic carbenes (NHC) as ancillary ligand. The palladium-mediated coupling reactions investigated include the Suzuki-Miyaura, Kumada-Tamao-Corriu, Heck, Sonogashira, Stille, Hiyama and aryl animation reactions. (C) 2002 Elsevier Science B.V. All rights reserved.
Original language | English |
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Pages (from-to) | 69-82 |
Number of pages | 14 |
Journal | Journal of Organometallic Chemistry |
Volume | 653 |
Issue number | 1-2 |
Publication status | Published - 1 Jul 2002 |
Keywords
- cross-coupling reactions
- N-heterocyclic carbenes
- palladium
- N-HETEROCYCLIC CARBENES
- PALLADIUM/IMIDAZOLIUM CHLORIDE SYSTEM
- HYPERVALENT SILOXANE DERIVATIVES
- OLEFIN METATHESIS CATALYSTS
- ROOM-TEMPERATURE AMINATION
- NICKEL-PHOSPHINE COMPLEXES
- HIGHLY-ACTIVE CATALYST
- ARYL CHLORIDES
- HECK REACTION
- ORGANIC HALIDES