Catalytic and Structural Studies of Hoveyda-Grubbs Type Pre-Catalysts Bearing Modified Ether Ligands

Stefano Guidone, Enguerrand Blondiaux, Cezary Samojlowicz, Lukasz Gulajski, Mariusz Kedziorek, Maura Malinska, Aleksandra Pazio, Krzysztof Wozniak, Karol Grela, Angelino Doppiu, Catherine S. J. Cazin

Research output: Contribution to journalArticlepeer-review

Abstract

Catalytic and crystallographic studies of HoveydaGrubbs type pre-catalysts M51TM and M52TM were performed. These two new instruments in the olefin metathesis catalyst toolbox were shown to be active at ambient temperature and at low loading, leading to clean formation of ring-closing, ring-closing enyne and cross metathesis products.

Original languageEnglish
Pages (from-to)2734-2742
Number of pages9
JournalAdvanced Synthesis & Catalysis
Volume354
Issue number14-15
DOIs
Publication statusPublished - Oct 2012

Keywords

  • N-heterocycle carbenes
  • Olefin metathesis
  • Ring-closing metathesis
  • Ruthenium

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