Carboxylation of C-H bonds using N-heterocyclic carbene gold(I) complexes

Ine Ida Fransoise Boogaerts; Steven Patrick Nolan

doi:10.1021/ja103429q

Carboxylation of C-H bonds using N-heterocyclic carbene gold(I) complexes

Ine Ida Fransoise Boogaerts, Steven Patrick Nolan

Research output: Contribution to journal › Article › peer-review

Abstract

A highly efficient [(NHC)Au-1]-based (NHC = N-heterocyclic carbene) catalytic system for the carboxylation of aromatic and heteroaromatic C-H bonds was developed. The significant base strength of the Au-OH species is at the origin of the activation process and permits the facile functionalization of C-H bonds without the use of other organometallic reagents.

Original language	English
Pages (from-to)	8858-8859
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	132
Issue number	26
DOIs	https://doi.org/10.1021/ja103429q
Publication status	Published - 7 Jul 2010

Keywords

Carbon-Dioxide
Chemoselective Carboxylation
Copper(I) Complexes
CO2
Esters
Acids
Activation
Halides

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10.1021/ja103429q

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title = "Carboxylation of C-H bonds using N-heterocyclic carbene gold(I) complexes",

abstract = "A highly efficient [(NHC)Au-1]-based (NHC = N-heterocyclic carbene) catalytic system for the carboxylation of aromatic and heteroaromatic C-H bonds was developed. The significant base strength of the Au-OH species is at the origin of the activation process and permits the facile functionalization of C-H bonds without the use of other organometallic reagents.",

keywords = "Carbon-Dioxide, Chemoselective Carboxylation, Copper(I) Complexes, CO2, Esters, Acids, Activation, Halides",

author = "Boogaerts, {Ine Ida Fransoise} and Nolan, {Steven Patrick}",

note = "Financial support for this work was provided by the EPSRC and the ERC (FUNCAT).",

year = "2010",

month = jul,

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doi = "10.1021/ja103429q",

language = "English",

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journal = "Journal of the American Chemical Society",

issn = "0002-7863",

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T1 - Carboxylation of C-H bonds using N-heterocyclic carbene gold(I) complexes

AU - Boogaerts, Ine Ida Fransoise

AU - Nolan, Steven Patrick

N1 - Financial support for this work was provided by the EPSRC and the ERC (FUNCAT).

PY - 2010/7/7

Y1 - 2010/7/7

N2 - A highly efficient [(NHC)Au-1]-based (NHC = N-heterocyclic carbene) catalytic system for the carboxylation of aromatic and heteroaromatic C-H bonds was developed. The significant base strength of the Au-OH species is at the origin of the activation process and permits the facile functionalization of C-H bonds without the use of other organometallic reagents.

AB - A highly efficient [(NHC)Au-1]-based (NHC = N-heterocyclic carbene) catalytic system for the carboxylation of aromatic and heteroaromatic C-H bonds was developed. The significant base strength of the Au-OH species is at the origin of the activation process and permits the facile functionalization of C-H bonds without the use of other organometallic reagents.

KW - Carbon-Dioxide

KW - Chemoselective Carboxylation

KW - Copper(I) Complexes

KW - CO2

KW - Esters

KW - Acids

KW - Activation

KW - Halides

UR - http://www.scopus.com/inward/record.url?scp=77954271854&partnerID=8YFLogxK

U2 - 10.1021/ja103429q

DO - 10.1021/ja103429q

M3 - Article

SN - 0002-7863

VL - 132

SP - 8858

EP - 8859

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 26

ER -

Carboxylation of C-H bonds using N-heterocyclic carbene gold(I) complexes

Abstract

Keywords

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Other files and links

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Molecular assembly using gold catalysis: Molecular assembly using gold catalysis

FUNCAT: EU FP7 ERC Advanced Grant - FUNCAT - Fundamental Studies in Organometallic Chemistry and Homogeneous Catalysis

Cite this

Carboxylation of C-H bonds using N-heterocyclic carbene gold(I) complexes

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Projects

Molecular assembly using gold catalysis: Molecular assembly using gold catalysis

FUNCAT: EU FP7 ERC Advanced Grant - FUNCAT - Fundamental Studies in Organometallic Chemistry and Homogeneous Catalysis

Cite this