Projects per year
Abstract
SwitchPhos: Rhodium complexes formed from PPh3 ligands functionalized with weakly basic amidine groups are highly active catalysts for the hydroformylation of alkenes. On bubbling with CO2 in the presence of water, the yellow rhodium complexes move into the water phase, whereas bubbling with N2 at 60 °C causes them to switch back into the organic phase. The catalysts can be used for reactions in water or an organic phase.
Original language | English |
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Pages (from-to) | 1472-1474 |
Number of pages | 3 |
Journal | Angewandte Chemie International Edition |
Volume | 48 |
Issue number | 8 |
DOIs | |
Publication status | Published - 9 Feb 2009 |
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Dive into the research topics of 'Carbon Dioxide Induced Phase Switching for Homogeneous-Catalyst Recycling'. Together they form a unique fingerprint.Projects
- 1 Finished
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Multinucleur NMR: Multinuclear NMR in support of synthetic and materials chemistry at UoS
Philp, D. (PI), Lebl, T. (CoI) & O'Hagan, D. (CoI)
1/01/06 → 2/04/09
Project: Standard