Capto-dative stabilisation in amino-substituted radicals

Iain MacInnes; John C. Walton; Derek C. Nonhebel

doi:10.1039/c39850000712

Capto-dative stabilisation in amino-substituted radicals

Iain MacInnes
, John C. Walton^*
, Derek C. Nonhebel

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

The rotational barriers about the C-N bonds in aminoalkyl radicals, H ₂NĊHR, were found to be significantly greater when R is an acceptor group than when R is an alkyl group; this is good evidence for capto-dative stabilisation of the ground state radicals.

Original language	English
Pages (from-to)	712-713
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	11
DOIs	https://doi.org/10.1039/c39850000712
Publication status	Published - 1 Jan 1985

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title = "Capto-dative stabilisation in amino-substituted radicals",

abstract = "The rotational barriers about the C-N bonds in aminoalkyl radicals, H 2NĊHR, were found to be significantly greater when R is an acceptor group than when R is an alkyl group; this is good evidence for capto-dative stabilisation of the ground state radicals.",

author = "Iain MacInnes and Walton, \{John C.\} and Nonhebel, \{Derek C.\}",

year = "1985",

month = jan,

day = "1",

doi = "10.1039/c39850000712",

language = "English",

pages = "712--713",

journal = "Journal of the Chemical Society, Chemical Communications",

issn = "0022-4936",

publisher = "Chemical Society",

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T1 - Capto-dative stabilisation in amino-substituted radicals

AU - MacInnes, Iain

AU - Walton, John C.

AU - Nonhebel, Derek C.

PY - 1985/1/1

Y1 - 1985/1/1

N2 - The rotational barriers about the C-N bonds in aminoalkyl radicals, H 2NĊHR, were found to be significantly greater when R is an acceptor group than when R is an alkyl group; this is good evidence for capto-dative stabilisation of the ground state radicals.

AB - The rotational barriers about the C-N bonds in aminoalkyl radicals, H 2NĊHR, were found to be significantly greater when R is an acceptor group than when R is an alkyl group; this is good evidence for capto-dative stabilisation of the ground state radicals.

UR - https://www.scopus.com/pages/publications/37049103210

U2 - 10.1039/c39850000712

DO - 10.1039/c39850000712

M3 - Article

AN - SCOPUS:37049103210

SN - 0022-4936

SP - 712

EP - 713

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 11

ER -

Capto-dative stabilisation in amino-substituted radicals

Abstract

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