Bridging (thionylimido)metal complexes

Liam J. R. McGeachie; Michael Buehl; David B. Cordes; Alexandra Martha Zoya Slawin; J Derek Woollins

doi:10.1021/acs.inorgchem.1c00725

Bridging (thionylimido)metal complexes

Liam J. R. McGeachie, Michael Buehl, David B. Cordes, Alexandra Martha Zoya Slawin, J Derek Woollins

Research output: Contribution to journal › Article › peer-review

Abstract

We report the first examples of the thionylimido ligand acting as a μ₂-bridging ligand between two transition-metal centers; using Cp₂Ti(NSO)₂, we describe bi- and tetrametallic systems.

Original language	English
Number of pages	5
Journal	Inorganic Chemistry
Volume	Articles ASAP
Early online date	27 May 2021
DOIs	https://doi.org/10.1021/acs.inorgchem.1c00725
Publication status	E-pub ahead of print - 27 May 2021

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10.1021/acs.inorgchem.1c00725Licence: CC BY-NC-ND

McGeachie_2021_IC_Bridging_CC
Copyright © 2021 The Authors. Published by American Chemical Society. This is an open access article under the terms of the Creative Commons Attribution-NonCommercial-NoDerivs License, which permits use and distribution in any medium, provided the original work is properly cited, the use is non-commercial and no modifications or adaptations are made.
Final published version, 2.65 MBLicence: CC BY-NC-ND

Bridging Thionylimido Metal Complexes (dataset)
McGeachie, L. J. R. (Creator), Buehl, M. (Creator), Cordes, D. B. (Creator), Slawin, A. M. Z. (Creator) & Woollins, J. D. (Creator), University of St Andrews, 2 Jun 2021
DOI: 10.17630/0bf163c5-ad55-4e38-a245-e15c5630eb16
Dataset

File
CCDC 1985296: Experimental Crystal Structure Determination
McGeachie, L. J. R. (Creator), Bühl, M. (Creator), Cordes, D. B. (Creator), Slawin, A. M. Z. (Creator) & Woollins, J. D. (Creator), Cambridge Crystallographic Data Centre, 2021
DOI: 10.5517/ccdc.csd.cc24mvtg, https://dx.doi.org/10.5517/ccdc.csd.cc24mvvh and 3 more links, https://dx.doi.org/10.5517/ccdc.csd.cc24mvwj, https://dx.doi.org/10.5517/ccdc.csd.cc24mvxk, https://dx.doi.org/10.5517/ccdc.csd.cc24mvyl (show fewer)
Dataset

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@article{290a37e437f24b5fb09bdb47dad6635c,

title = "Bridging (thionylimido)metal complexes",

abstract = "We report the first examples of the thionylimido ligand acting as a μ2-bridging ligand between two transition-metal centers; using Cp2Ti(NSO)2, we describe bi- and tetrametallic systems.",

author = "McGeachie, {Liam J. R.} and Michael Buehl and Cordes, {David B.} and Slawin, {Alexandra Martha Zoya} and Woollins, {J Derek}",

note = "L.J.R.M. is grateful to EPSRC for a provision of Ph.D. funding. M.B. thanks the School of Chemistry and EaStCHEM for support.",

year = "2021",

month = may,

day = "27",

doi = "10.1021/acs.inorgchem.1c00725",

language = "English",

volume = "Articles ASAP",

journal = "Inorganic Chemistry",

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TY - JOUR

T1 - Bridging (thionylimido)metal complexes

AU - McGeachie, Liam J. R.

AU - Buehl, Michael

AU - Cordes, David B.

AU - Slawin, Alexandra Martha Zoya

AU - Woollins, J Derek

N1 - L.J.R.M. is grateful to EPSRC for a provision of Ph.D. funding. M.B. thanks the School of Chemistry and EaStCHEM for support.

PY - 2021/5/27

Y1 - 2021/5/27

N2 - We report the first examples of the thionylimido ligand acting as a μ2-bridging ligand between two transition-metal centers; using Cp2Ti(NSO)2, we describe bi- and tetrametallic systems.

AB - We report the first examples of the thionylimido ligand acting as a μ2-bridging ligand between two transition-metal centers; using Cp2Ti(NSO)2, we describe bi- and tetrametallic systems.

U2 - 10.1021/acs.inorgchem.1c00725

DO - 10.1021/acs.inorgchem.1c00725

M3 - Article

SN - 0020-1669

VL - Articles ASAP

JO - Inorganic Chemistry

JF - Inorganic Chemistry

ER -

Bridging (thionylimido)metal complexes

Abstract

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Datasets

Bridging Thionylimido Metal Complexes (dataset)

CCDC 1985296: Experimental Crystal Structure Determination

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