Abstract
This article focuses on contemporary applications of boron complexes in organic synthesis—where the unique reactivity of B-containing reagents or catalysts is integral to a synthetic purpose. The coverage includes major developments and new research areas such as transition metal-free borylation and cross-coupling processes, photoredox methodologies, the emergence of catalytic processes using B-containing catalysts, and the advances made in the use of metalate and boryl anion strategies.
Original language | English |
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Title of host publication | Comprehensive organometallic chemistry IV |
Subtitle of host publication | Volume 11, Applications I. Main group complexes in organic synthesis |
Editors | David J. Liptrot, Gerard Parkin, Karsten Meyer, Dermot O'Hare |
Place of Publication | Amsterdam |
Publisher | Elsevier Inc. |
Chapter | 7 |
Pages | 305-334 |
Number of pages | 30 |
Volume | 11 |
Edition | 4th |
ISBN (Electronic) | 9780323913508 |
ISBN (Print) | 9780443185533, 9780128202067 |
DOIs | |
Publication status | Published - 5 Aug 2022 |
Keywords
- Boron
- Catalysis
- Complexes
- Cross-coupling
- Nucleophilic addition
- Photoredox
- Synthesis